Abstract
AuCl −4 + jOH− + kH2O = AuCl4 − j − k OH j (H2O) k − 1 k + (j + k)Cl− equilibria at 20°C were studied spectrophotometrically, and the constants β jk in acid aqueous solutions were determined for I = 2.0 mol/L (HClO4).
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References
N. Bjerrum, Bull. Soc. Chim. Belg. 57, 432 (1948).
H. Chateau, M. C. Gadet, and J. Pouradier, J. Chim. Phys. Phys.-Chim. Biol. 63, 269 (1966).
I. V. Mironov and L. D. Tsvelodub, Zh. Neorg. Khim. 45(4), 706 (2000) [Russ. J. Inorg. Chem. 45 (4), 633 (2000)].
B. I. Peshchevitskii, V. I. Belevantsev, and N. V. Kurbatova, Zh. Neorg. Khim. 16(7), 1898 (1971).
V. I. Belevantsev, A. P. Ryzhikh, E. V. Makotchenko, and V. I. Malkova, Zh. Neorg. Khim. 44(4), 608 (1999) [Russ. J. Inorg. Chem. 44 (4), 554 (1999)].
I. V. Mironov, Zh. Neorg. Khim. 50(7), 1204 (2005) [Russ. J. Inorg. Chem. 50 (7), 1115 (2005)].
I. V. Mironov and E. V. Makotchenko, Zh. Neorg. Khim. 50(5), 875 (2005) [Russ. J. Inorg. Chem. 50 (5), 799 (2005)].
V. I. Belevantsev and I. V. Mironov, Zh. Neorg. Khim. 27(6), 1392 (1982).
Yu. V. Karyakin and I. I. Angelov, Pure Chemicals (Khimiya, Moscow, 1974) [in Russian].
F. Hartley, C. Burgess, and R. Alcoc, Solution Equilibria (Ellis Hartwood, Chichester (U.K.), 1980; Mir, Moscow, 1983).
V. I. Belevantsev and B. I. Peshchevitskii, Investigations of Complex Equilibria in Solution (Nauka, Novosibirsk, 1978) [in Russian].
I. Nagypal and M. Beck, Talanta 29, 473 (1982).
S. Sjoberg, Acta Chem. Scand. A31, 705 (1977).
B. I. Peshchevitskii, V. I. Belevantsev, and S. V. Zemskov, Izv. Sib. Otd. Akad. Nauk SSSR, No. 2, 24 (1976).
L. H. Skibsted and N. Bjerrum, J. Indian Chem. Soc. LIV, 102 (1977).
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Original Russian Text © I.V. Mironov, E.V. Makotchenko, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 12, pp. 2091–2099.
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Mironov, I.V., Makotchenko, E.V. Equilibria in the system of aquachlorohydroxogold(III) complexes in aqueous solution. Russ. J. Inorg. Chem. 54, 2010–2017 (2009). https://doi.org/10.1134/S0036023609120298
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DOI: https://doi.org/10.1134/S0036023609120298