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Oxidation of the iron(II) complex with 3,5-dimethylpyrazole by air in acetonitrile and dibenzyl ether

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Abstract

The reaction of the polymeric complex FeCl2(NCMe)2 (1) with 3,5-dimethylpyrazole (Hdmpz) yields the tetrahedral complex [Fe(Hdmpz)3Cl]Cl (2), which is oxidized by air in acetonitrile to give [Fe(Hdmpz)3Cl2]2(μ-O) (3). The reaction of FeCl3 · 6H2O with Hdmpz also leads to complex 3. The oxidation of complex 2 in a dichloromethane solution of dibenzyl ether gives the complex (Hdmpz)FeCl2[η2-N,O-(dmpz)C(O)H(Ph)] (4), which contains a coordinated tetrahedral intermediate product of condensation of Hdmpz and benzaldehyde. The structures of complexes 1–4 are discussed on the basis of X-ray crystallographic data.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    E. V. Perova & S. E. Nefedov

  2. Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Lustdorfskaya doroga 86, Odessa, 65080, Ukraine

    D. G. Chikhichin & G. L. Kamalov

Authors
  1. E. V. Perova
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  2. S. E. Nefedov
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  3. D. G. Chikhichin
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  4. G. L. Kamalov
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Correspondence to S. E. Nefedov.

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Original Russian Text © E.V. Perova, S.E. Nefedov, D.G. Chikhichin, G.L. Kamalov, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 12, pp. 2018–2028.

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Perova, E.V., Nefedov, S.E., Chikhichin, D.G. et al. Oxidation of the iron(II) complex with 3,5-dimethylpyrazole by air in acetonitrile and dibenzyl ether. Russ. J. Inorg. Chem. 54, 1936–1946 (2009). https://doi.org/10.1134/S003602360912016X

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  • DOI: https://doi.org/10.1134/S003602360912016X

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