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Ribbon structure of the coordination polymer of silver trifluoroacetate with 2-pyrimidinecarboxamide

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Abstract

Complex [Ag(CF3CO2)(C5H5N3O)] (I) was synthesized, and its structure was determined. Crystals of complex I are triclinic, space group P \( \bar 1 \),,a = 7.325(1) Å, b = 7.554(1) Å, c = 10.527(1) Å, α = 94.25(1)°, β = 96.19(1)°, γ = 117.75(1)°, V = 507.4(1) Å3, ρcalcd = 2.252 g/cm3, Z = 2. Structure I contains dimeric silver carboxylates Ag2(C5H5N3O) 2+2 , formed by 2-pyrimidinecarboxamide. Adjacent dimers Ag2(C5H5N3O) 2+2 are linked by carboxylate dimers to form infinite ribbons along the x axis. The ribbons are arranged in the structure so that cavities are formed between them in the [001] direction. Trifluoroacetate CF3 groups and carboxamide NH2 groups are directed into the inside of these cavities.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    Yu. V. Kokunov, Yu. E. Gorbunova & V. V. Kovalev

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  1. Yu. V. Kokunov
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  2. Yu. E. Gorbunova
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  3. V. V. Kovalev
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Original Russian Text © Yu.V. Kokunov, Yu.E. Gorbunova, V.V. Kovalev, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 12, pp. 1992–1996.

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Kokunov, Y.V., Gorbunova, Y.E. & Kovalev, V.V. Ribbon structure of the coordination polymer of silver trifluoroacetate with 2-pyrimidinecarboxamide. Russ. J. Inorg. Chem. 54, 1909–1913 (2009). https://doi.org/10.1134/S0036023609120110

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  • DOI: https://doi.org/10.1134/S0036023609120110

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