Skip to main content
SpringerLink
Log in

Conformational rearrangement of 18-crown-6 upon the formation of aquanitratouranyl complexes: The refinement of crystal and molecular structures for [UO2(NO3)2(H2O)2] · 2H2O · 18C6

  • Coordination Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Comparing the geometry of [UO2(NO3)2(H2O)2] · 2H2O · 18C6 (18C6 = C12H24O6) and IR spectroscopic data, we propose correlations between the conformation of an ethylene oxide unit of 18-crown-6 and the conformation-sensitive frequency in the IR spectrum. Spectral conformational analysis verifies the composition of the 18-crown-6 conformer in the [UO2(NO3)2(H2O)2] · 18C6 complex whose structure is known. The distribution character of hydrogen bonds that retain crown ether molecules in aquanitratouranyl complexes is shown to influence the conformational uniformity of ethylene oxide units of the macrocycle.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. I. Belomestnykh, L. B. Sveshnikova, Yu. N. Mikhailov, et al., Zh. Neorg. Khim. 49(7), 1110 (2004) [Russ. J. Inorg. Chem. 49 (7), 1016 (2004)].

    CAS  Google Scholar 

  2. V. I. Belomestnykh and L. B. Sveshnikova, Zh. Neorg. Khim. 51(9), 1550 (2006) [Russ. J. Inorg. Chem. 51 (9), 1458 (2006)].

    CAS  Google Scholar 

  3. P. G. Eller and R. A. Penneman, Inorg. Chem. 15(10), 2439 (1976).

    Article  CAS  Google Scholar 

  4. G. Bombieri, G. De Paoli, and A. Immirzi, J. Inorg. Nucl. Chem. 40(5), 799 (1978).

    Article  CAS  Google Scholar 

  5. V. I. Belomestnykh, L. B. Sveshnikova, and K. S. Shabel’nik, Koord. Khim. 16(10), 1433 (1990).

    CAS  Google Scholar 

  6. G. M. Sheldrick, Acta Crystallogr., Sect. A 46(3), 463 (1990).

    Google Scholar 

  7. G. M. Sheldrick, Program for the Refinement of Crystal Structures (Univ. of Göttingen, Göttingen, 1997).

    Google Scholar 

  8. N. A. Chumaevskii, V. I. Belomestnykh, G. A. Razgonyaeva, et al., Coord. Khim. 14(10), 1411 (1988).

    CAS  Google Scholar 

  9. L. V. Volod’ko, A. I. Komyak, and D. S. Umreiko, Uranyl Compounds (BGU, Minsk, 1981) [in Russian].

    Google Scholar 

  10. L. V. Vdovenko, E. V. Stroganov, and A. N. Sokolov, Radiokhimiya 5(1), 97 (1963).

    CAS  Google Scholar 

  11. V. M. Vdovenko, E. V. Stroganov, and A. N. Sokolov, Radiokhimiya 4(1), 59 (1962).

    CAS  Google Scholar 

  12. I. C. Taylor and M. H. Mueller, Acta Crystallogr. 19(4), 536 (1965).

    Article  CAS  Google Scholar 

  13. A. V. Karyakin and G. A. Kriventsova, State of Water in Organic and Inorganic Compounds (Nauka, Moscow, 1973) [in Russian].

    Google Scholar 

  14. A. Yu. Tsivadze, A. A. Varnek, and V. E. Khutorskii, Coordination Compounds of Metals with Crown Ligands (Nauka, Moscow, 1991) [in Russian].

    Google Scholar 

  15. I. K. Kireeva, N. B. Generalova, A. Yu. Tsivadze, et al., Zh. Inorg. Khim. 43(9), 1501 (1998) [Russ. J. Inorg. Chem. 43 (9), 1387 (1998)].

    CAS  Google Scholar 

  16. V. A. Trofimov, I. K. Kireeva, N. B. Generalova, and A. Yu. Tsivadze, Koord. Khim. 16(11), 1458 (1990).

    CAS  Google Scholar 

  17. J. D. Dunitz and P. Seifer, Acta Crystallogr., Sect. B 30(11) 2739 (1974).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    Yu. N. Mikhailov, L. B. Sveshnikova, A. S. Kanishcheva, V. I. Belomestnykh & A. V. Churakov

Authors
  1. Yu. N. Mikhailov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. B. Sveshnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. S. Kanishcheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. I. Belomestnykh
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. V. Churakov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © Yu.N. Mikhailov, L.B. Sveshnikova, A.S. Kanishcheva, V.I. Belomestnykh, A.V. Churakov, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 12, pp. 1978–1984.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mikhailov, Y.N., Sveshnikova, L.B., Kanishcheva, A.S. et al. Conformational rearrangement of 18-crown-6 upon the formation of aquanitratouranyl complexes: The refinement of crystal and molecular structures for [UO2(NO3)2(H2O)2] · 2H2O · 18C6. Russ. J. Inorg. Chem. 54, 1895–1901 (2009). https://doi.org/10.1134/S0036023609120092

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023609120092

Keywords

Search

Navigation