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High-pressure defect phase Nd x Cu3V4O12

  • Synthesis and Properties of Inorganic Compounds
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Abstract

A perovskite-like oxide Nd x Cu3V4O12 (space group Im \( \bar 3 \) Z = 2, a = 7.278–7.322 Å) with cationic vacancies was prepared for the first time under triaxial compression of p = 6.0–9.0 GPa at 700–1300°C. The compound has a metal-type conductivity, paramagnetic properties, and a phase transition.

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Authors and Affiliations

  1. Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620219, Russia

    N. I. Kadyrova, Yu. G. Zainulin, V. L. Volkov & G. S. Zakharova

  2. Russian Academy of Sciences, ul. S. Kovalevskoi 18, Yekaterinburg, 620041, Russia

    A. V. Korolev

Authors
  1. N. I. Kadyrova
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  2. Yu. G. Zainulin
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  3. V. L. Volkov
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  4. G. S. Zakharova
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  5. A. V. Korolev
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Original Russian Text © N.I. Kadyrova, Yu.G. Zainulin, V.L. Volkov, G.S. Zakharova, A.V. Korolev, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 12, pp. 1954–1957.

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Kadyrova, N.I., Zainulin, Y.G., Volkov, V.L. et al. High-pressure defect phase Nd x Cu3V4O12 . Russ. J. Inorg. Chem. 54, 1872–1875 (2009). https://doi.org/10.1134/S0036023609120043

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  • DOI: https://doi.org/10.1134/S0036023609120043

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