Skip to main content
SpringerLink
Log in

Synthesis, IR spectra, and solid-state luminescence of triphenylguanidinium salts with the anions B10H 2−10 , B12H 2−12 , B9C2H 2−12 , [Co(C2B9H11)2]−, and [Ni(C2B9H11)2]−

  • Synthesis and Properties of Inorganic Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Triphenylguanidinium Ph3GH+ salts with the anions B10H 2−10 , B12H 2−12 , B9C2H 2−12 , [Co(C2B9H11)2]−, and [Ni(C2B9H11)2]− were synthesized and described by DTA, IR spectroscopy, and solid-state luminescence. By IR spectroscopy, it was shown that intermolecular interactions involving the NH groups of the cation are enhanced in the sequence [Co(C2B9H11)2]− ∼ [Ni(C2B9H11)2]− < B9C2H 2−12 < B12H 2−12 < B10H 2−10 .

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. M. Polyanskaya, E. A. Il’inchik, V. V. Volkov, et al., Zh. Strukt. Khim. 49, 512 (2008).

    Google Scholar 

  2. V. V. Shelkovnikov, Z. M. Ivanova, N. A. Orlova, et al., Opt. Spektrosk. 96(6), 899 (2004) [Opt. Spectrosc. 96 (6), 824 (2004)].

    Article  Google Scholar 

  3. V. V. Volkov, E. A. Il’inchik, O. V. Volkov, and O. P. Yur’eva, Khim. Interesah Ustoich. Razvit. 8(1), 67 (2000).

    CAS  Google Scholar 

  4. A. A. Kemme, M. A. Rutkis, and Ya. A. Eidus, Izv. Akad. Nauk Latv. SSR, Ser. Khim., No. 5, 595 (1988).

  5. S. Nishizawa, Y. Kato, and N. Teramae, J. Am. Chem. Soc. 121(40), 9463 (1999).

    Article  CAS  Google Scholar 

  6. E. A. Malinina, L. V. Goeva, K. A. Solntsev, and N. T. Kuznetsov, Zh. Neorg. Khim. 36(9), 2414 (1991).

    CAS  Google Scholar 

  7. M. F. Hawthorne, D. C. Yong, T. D. Andrewes, et al., J. Am. Chem. Soc. 90(4), 879 (1968).

    Article  CAS  Google Scholar 

  8. K. G. Myakishev and V. V. Volkov, Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk No. 12 (5), 111 (1977).

  9. I. Georgieva, N. Mintcheva, N. Trendafilova, and M. Mitewa, Vibr. Spectrosc. 27(1), 153 (2001).

    Article  CAS  Google Scholar 

  10. V. V. Volkov, E. A. Il’inchik, G. S. Voronina, et al., Zh. Neorg. Khim. 40(5), 800 (1995).

    CAS  Google Scholar 

  11. E. A. Il’inchik, T. M. Polyanskaya, M. K. Drozdova, et al., Zh. Obshch. Khim. 75(10), 1620 (2005) [Russ. J. Gen. Chem. 75 (10), 1545 (2005)].

    Google Scholar 

  12. M. Gouterman and P. Sayer, Chem. Phys. Lett. 8(1), 126 (1971).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    E. A. Il’inchik, M. K. Drozdova, O. P. Yur’eva, K. G. Myakishev & V. V. Volkov

Authors
  1. E. A. Il’inchik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. K. Drozdova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. P. Yur’eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. K. G. Myakishev
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. V. Volkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © E.A. Il’inchik, M.K. Drozdova, O.P. Yur’eva, K.G. Myakishev, V.V. Volkov, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 12, pp. 1948–1953.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Il’inchik, E.A., Drozdova, M.K., Yur’eva, O.P. et al. Synthesis, IR spectra, and solid-state luminescence of triphenylguanidinium salts with the anions B10H 2−10 , B12H 2−12 , B9C2H 2−12 , [Co(C2B9H11)2]−, and [Ni(C2B9H11)2]− . Russ. J. Inorg. Chem. 54, 1866–1871 (2009). https://doi.org/10.1134/S0036023609120031

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023609120031

Keywords

Search

Navigation