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Uranyl aquahydroxylaminate complexes

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Abstract

Uranylaqua complexes with N-methyl-, N-ethyl-, N-isopropyl-, and N,N-dimethylhydroxylamines were studied. The structure of [UO2{(CH3)2NO}2(H2O)2] was determined by X-ray crystallography. The N, N -dimethylhydroxylaminate ion is coordinated to uranyl through the nitrogen and oxygen atoms with the formation of a three-membered chelate ring.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. G. Beirakhov, I. M. Orlova, E. G. Il’in, A. V. Churakov, A. S. Kanishcheva & Yu. N. Mikhailov

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  1. A. G. Beirakhov
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  2. I. M. Orlova
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  3. E. G. Il’in
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  4. A. V. Churakov
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  5. A. S. Kanishcheva
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  6. Yu. N. Mikhailov
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Original Russian Text © A.G. Beirakhov, I.M. Orlova, E.G. Il’in, A.V. Churakov, A.S. Kanishcheva, Yu.N. Mikhailov, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 8, pp. 1282–1287.

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Beirakhov, A.G., Orlova, I.M., Il’in, E.G. et al. Uranyl aquahydroxylaminate complexes. Russ. J. Inorg. Chem. 54, 1217–1222 (2009). https://doi.org/10.1134/S0036023609080087

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  • DOI: https://doi.org/10.1134/S0036023609080087

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