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Cation mobility in modified Li1 + x Ti2 − x Ga x (PO4)3 lithium titanium NASICON phosphates

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Li1 +x Ti2 − x Ga x (PO4)3(x= 0−0.2) NASICON double phosphates are prepared and studied by high-temperature X-ray diffraction, 7Li NMR spectroscopy, impedance spectroscopy, and calorimetry. Doping with Ga3+ cations increases cation mobility in LiTi2(PO4)3. Ion conductivity, NMR spectroscopy, and calorimetry data imply the occurrence of a phase transition in LiTi2(PO4)3 and in products of partial gallium-for-titanium substitution.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    I. Yu. Pinus & A. B. Yaroslavtsev

  2. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    I. V. Arkhangel’skii

  3. Institute of Solid-State Chemistry, Ural Division, Russian Academy of Sciences, ul. Pervomaiskaya 91, Yekaterinburg, 620219, Russia

    N. A. Zhuravlev

Authors
  1. I. Yu. Pinus
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  2. I. V. Arkhangel’skii
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  3. N. A. Zhuravlev
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  4. A. B. Yaroslavtsev
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Original Russian Text © I.Yu. Pinus, I.V. Arkhangel’skii, N.A. Zhuravlev, A.B. Yaroslavtsev, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 8, pp. 1235–1239.

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Pinus, I.Y., Arkhangel’skii, I.V., Zhuravlev, N.A. et al. Cation mobility in modified Li1 + x Ti2 − x Ga x (PO4)3 lithium titanium NASICON phosphates. Russ. J. Inorg. Chem. 54, 1173–1176 (2009). https://doi.org/10.1134/S0036023609080014

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  • DOI: https://doi.org/10.1134/S0036023609080014

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