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Synthesis and study of the phosphate Cs2Mn0.5Zr1.5(PO4)3

  • Synthesis and Properties of Inorganic Compounds
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Abstract

The new phosphate Cs2Mn0.5Zr1.5(PO4)3 was synthesized for the first time and characterized by X-ray diffraction. Its crystal structure was refined in space group P213, Z = 4 at 25°C (a = 10.3163(1) Å, V = 1097.93(1) Å3), by the Rietveld method using the powder X-ray diffraction data. The structure is built of an octahedral-tetrahedral framework {[Mn0.5Zr1.5(PO4)3]2−}3∞ with cesium atoms being located in large cavities. The hydrolytic stability of the powdered phosphate containing 137Cs radionuclide was studied. The minimum achieved 137Cs leaching rate was 4 × 10−8 g/cm2 day.

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Authors and Affiliations

  1. Mayak Production Association, Ozersk, Russia

    A. R. Zaripov, V. A. Orlova, O. M. Slyunchev & D. D. Galuzin

  2. Nizhni Novgorod State University, pr. Gagarina 23, Nizhni Novgorod, 603950, Russia

    V. I. Pet’kov

Authors
  1. A. R. Zaripov
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  2. V. A. Orlova
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  3. V. I. Pet’kov
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  4. O. M. Slyunchev
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  5. D. D. Galuzin
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  6. S. I. Rovnyi
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Original Russian Text © A.R. Zaripov, V.A. Orlova, V.I. Pet’kov, O.M. Slyunchev, D.D. Galuzin, S. I. Rovnyi, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 1, pp. 47–52.

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Zaripov, A.R., Orlova, V.A., Pet’kov, V.I. et al. Synthesis and study of the phosphate Cs2Mn0.5Zr1.5(PO4)3 . Russ. J. Inorg. Chem. 54, 45–51 (2009). https://doi.org/10.1134/S0036023609010112

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  • DOI: https://doi.org/10.1134/S0036023609010112

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