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Low-temperature heat capacity and thermal behavior of Zn0.98Co0.02O in the high-temperature region

  • Synthesis and Properties of Inorganic Compounds
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Abstract

The low-temperature heat capacity of Zn 0.98Co0.02O oxide was measured by adiabatic calorimetry. The formation of a solid solution was shown to be accompanied by a change in the entropy by 0.4 J/(K mol). No anomalies in the heat capacity or the thermal behavior confirming the phase transformations found earlier by other methods were observed. A heat capacity anomaly was revealed below 15 K and tentatively attributed to a change in the magnetic properties of the substance.

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Correspondence to K. S. Gavrichev.

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Original Russian Text © K.S. Gavrichev, A.V. Tyurin, M.A. Ryumin, A.V. Khoroshilov, G.D. Nipan, V.A. Ketsko, T.N. Kol’tsova, I.Yu. Pinus, G.A. Buzanov, N.A. Votinova, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 1, pp. 3–7.

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Gavrichev, K.S., Tyurin, A.V., Ryumin, M.A. et al. Low-temperature heat capacity and thermal behavior of Zn0.98Co0.02O in the high-temperature region. Russ. J. Inorg. Chem. 54, 1–5 (2009). https://doi.org/10.1134/S003602360901001X

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  • DOI: https://doi.org/10.1134/S003602360901001X

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