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Modular approach as applied to the description, prediction, and targeted synthesis of bismuth oxohalides with layered structures

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Abstract

A version of the modular approach to the description, crystal-chemical analysis, and prediction of layered compounds is proposed. Criteria for the existence of new compounds with set structures are formulated and considered in detail for layered bismuth compounds. The potential of this approach is verified by the successful synthesis of more than 100 new bismuth oxohalides, which refer to more than ten predicted structure types.

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Charkin, D.O. Modular approach as applied to the description, prediction, and targeted synthesis of bismuth oxohalides with layered structures. Russ. J. Inorg. Chem. 53, 1977–1996 (2008). https://doi.org/10.1134/S0036023608130019

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