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Tetramminenickel hydrogen hexamolybdometalates(III)

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Tetramminenickel hydrogen hexamolybdoaluminate and hexamolybdogallate(III) of compositions [Ni(NH3)4] · H[AlMo6O18(OH)6] · 10H2O (I) and [Ni(NH3)4] · H[GaMo6O18(OH)6] · 10H2O (II) were synthesized and characterized by mass spectrometry, thermogravimetry, X-ray powder diffraction, and IR spectroscopy. Their crystals are triclinic. For compound I, a= 17.30 Å, b= 14.69 Å, c= 10.45 Å, α = 129.07, β = 65.91°, γ = 138.01°, V = 1338.7l Å3, ρcalcd = 2.75g/cm3, Z = 2; for compound II, a = 17.38 Å, b= 14.75 Å, c= 10.51 Å, α = 131.38°, β= 65.96°, γ = 138.09, V = 1338.15 Å3, ρcalcd = 2.68 g/cm3, Z = 2.

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Authors and Affiliations

  1. Moscow State Pedagogical University, Malaya Pirogovskaya ul. 1, Moscow, 119882, Russia

    A. V. Oreshkina & G. Z. Kaziev

  2. Moscow State University, Moscow, 119991, Russia

    T. Yu. Glazunova

Authors
  1. A. V. Oreshkina
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  2. G. Z. Kaziev
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  3. T. Yu. Glazunova
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Original Russian Text © A.V. Oreshkina, G.Z. Kaziev, T.Yu. Glazunova, 2008, published in Zhurnal Neorganicheskoi Khimii, 2008, Vol. 53, No. 10, pp. 1662–1666.

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Oreshkina, A.V., Kaziev, G.Z. & Glazunova, T.Y. Tetramminenickel hydrogen hexamolybdometalates(III). Russ. J. Inorg. Chem. 53, 1552–1556 (2008). https://doi.org/10.1134/S0036023608100057

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  • DOI: https://doi.org/10.1134/S0036023608100057

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