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Adducts of tetraphenylstibium nitrate with nitric acid and of tetraphenylstibium acetate with acetic acid: Syntheses and structures

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Abstract

The reactions of tetraphenylstibium nitrate with nitric acid and of tetraphenylstibium acetate with acetic acid yield adducts Ph4SbONO2 · HNO3 (I) and Ph4SbOC(O)CH3 · CHH3COOH (II). According to X-ray diffraction data, the antimony atom in [Ph4Sb]+[O2N-O···H···O-NO2]− has a tetrahedral coordination. The CSbC bond angles and Sb-C bond lengths vary within 108.04(6)°–109.75(4)° and 2.096(1)–2.098(1) Å, respectively. The anion includes the intermolecular hydrogen bond O(1)–H(1)···O(1)″: the O(1)-H(1), H(1)···O(1)″, and O(1)···O(1)″ distances are 0.91(4), 1.56(4), and 2.460(2) Å, respectively; and the OHO angle is 169(5)°. The nitrate groups are usually planar. Complex II also contains the intermolecular hydrogen bond with the following parameters: O(3)-H(3), 0.92 Å; H(3)···O(2), 1.68 Å; and O(3)···O(2) 2.594 Å; the O(2)H(3)O(3) angle is 172.1°. This H-bond noticeable changes the coordination polyhedron of the antimony atom compared to that in tetraphenylstibium acetate.

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, ul. Lenina 104, Blagoveshchensk, 675000, Russia

    V. V. Sharutin, V. S. Senchurin, O. K. Sharutina & L. P. Panova

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  1. V. V. Sharutin
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  2. V. S. Senchurin
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  3. O. K. Sharutina
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  4. L. P. Panova
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Original Russian Text © V.V. Sharutin, V.S. Senchurin, O.K. Sharutina, L.P. Panova, 2008, published in Zhurnal Neorganicheskoi Khimii, 2008, Vol. 53, No. 7, pp. 1194–1198.

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Sharutin, V.V., Senchurin, V.S., Sharutina, O.K. et al. Adducts of tetraphenylstibium nitrate with nitric acid and of tetraphenylstibium acetate with acetic acid: Syntheses and structures. Russ. J. Inorg. Chem. 53, 1110–1114 (2008). https://doi.org/10.1134/S0036023608070206

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  • DOI: https://doi.org/10.1134/S0036023608070206

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