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Synthesis and Structure of Co(III) Complexes with 2-Pyridinecarboxylic Acid

Russian Journal of Inorganic Chemistry volume 53, pages 202–208 (2008)Cite this article

Abstract

The Co(III) complexes with pyridinecarboxylic acid, Na[Co(Pc)2(NO2)2] (I) and NH4[Co(Pc)2(NO2)2] (II), where Pc is the 2-pyridinecarboxylate anion, have been synthesized and studied by X-ray diffraction. In the crystal, the complex anions are combined through the Na+ and NH +4 cations. In II, the anion and the cation are combined by hydrogen bonds.

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Authors and Affiliations

  1. Institute of Chemistry, Academy of Sciences of Moldova, Chisinau, Moldova

    G. Novitski

  2. Institute of Applied Physics, Academy of Sciences of Moldova, Chisinau, Moldova

    A. Borta, S. Shova & Yu. A. Simonov

  3. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    O. N. Kazheva

  4. Department of Chemistry, A. Mickiewicz University, Poznan, Poland

    M. Gdaniec

Authors
  1. G. Novitski
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  2. A. Borta
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  3. S. Shova
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  4. O. N. Kazheva
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  5. M. Gdaniec
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  6. Yu. A. Simonov
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Novitski, G., Borta, A., Shova, S. et al. Synthesis and Structure of Co(III) Complexes with 2-Pyridinecarboxylic Acid. Russ. J. Inorg. Chem. 53, 202–208 (2008). https://doi.org/10.1134/S0036023608020095

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  • DOI: https://doi.org/10.1134/S0036023608020095

Keywords

  • Complex Anion
  • Coordinate Water Molecule
  • Barium Sulfate
  • Cambridge Crystallographic Data Centre
  • Metal Carboxylate