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Study of nitrosation of hexaammineruthenium(II): Crystal structure of trans-[RuNO(NH3)4Cl]Cl2

  • Coordination Compounds
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Abstract

The nitrosation of [Ru(NH3)6]2+ in hydrochloric acid and alkaline ammonia media has been studied; the patterns of interconversion of ruthenium complexes in reaction solutions have been proposed. In both cases, nitrogen(II) oxide acts as the nitrosation agent. The procedure for the synthesis of [Ru(NO)(NH3)5]Cl3 · H2O (yield 75–80%), the main nitrosation product of [Ru(NH3)6]2+, has been optimized. Thermolysis of [Ru(NO)(NH3)5]Cl3 · H2O in a helium atmosphere has been studied; the intermediates have been identified. One of these products is polyamidodichloronitrosoruthenium(II) whose subsequent decomposition gives an equimolar mixture of ruthenium metal and dioxide. The structure of trans-[RuNO(NH3)4Cl]Cl2, formed in the second stage of thermolysis and as a by-product in the nitrosation of [Ru(NH3)6]Cl2, has been determined by X-ray diffraction.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    M. A. Il’in, V. A. Emel’yanov, I. A. Baidina, N. I. Alferova & I. V. Korol’kov

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  1. M. A. Il’in
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  2. V. A. Emel’yanov
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  3. I. A. Baidina
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  4. N. I. Alferova
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  5. I. V. Korol’kov
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Original Russian Text © M.A. Il’in, V.A. Emel’yanov, I.A. Baidina, N.I. Alferova, I.V. Korol’kov, 2007, published in Zhurnal Neorganicheskoi Khimii, 2007, Vol. 52, No. 1, pp. 67–75.

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Il’in, M.A., Emel’yanov, V.A., Baidina, I.A. et al. Study of nitrosation of hexaammineruthenium(II): Crystal structure of trans-[RuNO(NH3)4Cl]Cl2 . Russ. J. Inorg. Chem. 52, 62–70 (2007). https://doi.org/10.1134/S0036023607010123

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  • DOI: https://doi.org/10.1134/S0036023607010123

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