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Synthesis and properties of palladium(I) carbonyl chlorides

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Palladium(I) carbonyl chloride (PdCOCl) n has been synthesized by the effect of CO on PdCl2 in the presence of trace water. Anionic palladium(I) carbonyl chloride has been synthesized during treatment of ethanol-based or acetone-based solutions of H2PdCI4 containing small amounts of water; it has been isolated from the solution as the salt Cs2[Pd2(CO)2Cl4]. IR-spectra, X-ray diffraction patterns, and thermogravimetry data on synthesized palladium(I) carbonyl complexes are presented.

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Authors and Affiliations

  1. Kaluga Branch, Bauman State Technical University, Kaluga, Russia

    I. V. Fedoseev & A. S. Gordeev

Authors
  1. I. V. Fedoseev
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  2. A. S. Gordeev
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Additional information

Original Russian Text © I.V. Fedoseev, A.S. Gordeev, 2007, published in Zhurnal Neorganicheskoi Khimii, 2007, Vol. 52, No. 1, pp. 12–14.

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Fedoseev, I.V., Gordeev, A.S. Synthesis and properties of palladium(I) carbonyl chlorides. Russ. J. Inorg. Chem. 52, 7–9 (2007). https://doi.org/10.1134/S0036023607010020

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  • DOI: https://doi.org/10.1134/S0036023607010020

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