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Synthesis and crystal structure of tetranuclear platinum(II) complex [Pt4(μ-CH3COO)5(μ-NO)2(μ-NO2)]

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Abstract

A new tetranuclear complex [Pt4(μ-CH3COO)5(μ-NO)5(μ-NO)2(μ-NO2)]is synthesized by the reaction of K2Pt(NO2)4 with glacial acetic acid and studied by IR and electronic absorption spectroscopy. Its structure is determined by X-ray diffraction analysis. The metal core of the complex is a rectangle with short (2.937(1) Å) and long (3.289(1) Å) sides. Adjacent molecules in a crystal are bonded by weak Pt…Pt interactions (3.215(1) Å) to form chains extended along the crystallographic axis b.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    G. G. Aleksandrov, G. N. Kuznetsova & T. N. Fedotova

Authors
  1. G. G. Aleksandrov
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  2. G. N. Kuznetsova
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  3. T. N. Fedotova
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Original Russian Text © G.G. Aleksandrov, G.N. Kuznetsova, T.N. Fedotova, 2006, published in Zhurnal Neorganicheskoi Khimii, 2006, Vol. 51, No. 12, pp. 1989–1993.

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Aleksandrov, G.G., Kuznetsova, G.N. & Fedotova, T.N. Synthesis and crystal structure of tetranuclear platinum(II) complex [Pt4(μ-CH3COO)5(μ-NO)2(μ-NO2)]. Russ. J. Inorg. Chem. 51, 1872–1876 (2006). https://doi.org/10.1134/S0036023606120060

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  • DOI: https://doi.org/10.1134/S0036023606120060

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