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Electrochemical study of heteronuclear complex [Cp(CO)2MnCu(μ-C=CHPh)(μ-Cl)]2

  • Physical Methods of Investigation
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Abstract

The electrochemical behavior of the heteronuclear dimeric vinylidene complex [Cp(CO)2MnCu(μ-C=CHPh)(μ-Cl)]2 (I) is studied using polarography, cyclic voltammetry, and controlled-potential electrolysis on mercury and platinum electrodes in acetonitrile. The dimer is reduced in two two-electron stages: at the first stage, metal-halogen bonds are broken and binuclear monomers [Cp(CO)2MnCu(μ-C=CHPh)(Cl)]− are formed; at the second stage, mononuclear manganese complexes Cp(CO)2Mn=C=CHPh, metallic copper, and chloride ions are formed. The two-electron oxidation of dimer [Cp(CO)2MnCu(μ-C=CHPh)(μ-Cl)]2 also results in the formation of binuclear monomers, which decompose to complex Cp(CO)2Mn=C=CHPh, Cu2+ ions, and Cl− ions.

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Authors and Affiliations

  1. Institute of Chemistry and Chemical Technology, Siberian Division, Russian Academy of Sciences, ul. K. Marksa 42, Krasnoyarsk, 660049, Russia

    G. V. Burmakina, N. I. Pavlenko, A. B. Antonova, D. A. Pogrebnyakov & A. I. Rubailo

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  1. G. V. Burmakina
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  2. N. I. Pavlenko
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  3. A. B. Antonova
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  4. D. A. Pogrebnyakov
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  5. A. I. Rubailo
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Original Russian Text © G.V. Burmakina, N.I. Pavlenko, A.B. Antonova, D.A. Pogrebnyakov, A.I. Rubailo, 2006, published in Zhurnal Neorganicheskoi Khimii, 2006, Vol. 51, No. 5, pp. 851–855.

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Burmakina, G.V., Pavlenko, N.I., Antonova, A.B. et al. Electrochemical study of heteronuclear complex [Cp(CO)2MnCu(μ-C=CHPh)(μ-Cl)]2 . Russ. J. Inorg. Chem. 51, 785–789 (2006). https://doi.org/10.1134/S0036023606050160

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  • DOI: https://doi.org/10.1134/S0036023606050160

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