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Crystal structure and triboluminescence of the [Tb(BTFA)2(NO3)(TPPO)2] complex

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Abstract

The crystal structure of the [Tb(BTFA)2(NO3)(TPPO)2] complex (TPPO is triphenylphosphine oxide, BTFA is benzoyltrifluoracetone), which exhibits strong triboluminescence, has been established by X-ray crystallography. The crystals are triclinic: a = 11.668(3) Å, b = 11.700(3) Å, c = 12.512(3) Å, α = 65.161(4°), β = 79.120(4)°, γ = 61.860(4)°, space group P1, Z = 1. The central terbium(III) atom coordinates two oxygen atoms from two triphenylphosphine oxide molecules (Tb-O, 2.264(3) and 2.273(3) Å), two oxygen atoms from the nitrate group (Tb-O, 2.460(3) and 2.476(3) Å), and four oxygen atoms from two benzoyltrifluoroacetonate groups (Tb-O, 2.329(3), 2.399(3), 2.351(3), and 2.367(3) Å). The coordination polyhedron of the Tb(III) atom is a distorted dodecahedron. The photoluminescence and triboluminescence spectra of the [Tb(BTFA)2(NO3)(TPPO)2] complex are identical and caused by the f-f luminescence of Tb3+.

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Authors and Affiliations

  1. Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    A. G. Mirochnik, B. V. Bukvetskii, P. A. Zhikhareva, N. V. Polyakova & V. E. Karasev

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  1. A. G. Mirochnik
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  2. B. V. Bukvetskii
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  3. P. A. Zhikhareva
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  4. N. V. Polyakova
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  5. V. E. Karasev
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Original Russian Text © A. G. Mirochnik, B. V. Bukvetskii, P.A. Zhikhareva, N. V. Polyakova, V.E. Karasev, 2006, published in Zhurnal Neorganicheskoi Khimii, 2006, Vol. 51, No. 5, pp. 804–809.

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Mirochnik, A.G., Bukvetskii, B.V., Zhikhareva, P.A. et al. Crystal structure and triboluminescence of the [Tb(BTFA)2(NO3)(TPPO)2] complex. Russ. J. Inorg. Chem. 51, 737–742 (2006). https://doi.org/10.1134/S003602360605010X

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  • DOI: https://doi.org/10.1134/S003602360605010X

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