Abstract
The oxodiperoxo complexes of Mo(VI) of the type [MoO(O2)2L], where L = Morpholinomethyl urea, morpholinomethyl thiourea, piperidinomethyl urea, piperidinomethyl thiourea, pyrrolidinomethyl urea, and pyrrolidinomethyl thiourea have been synthesized and characterized by elemental analysis, molar conductance, IR, UV-Vis, and TGA/DTA techniques. It is shown that the ligands coordinate to the metal ion in a symmetrical bidentate fashion through heterocyclic nitrogen and carbonyl oxygen or thiocarbonyl sulfur. Thermal studies indicate continuous weight loss until a stable oxide is formed.
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Sheikh, H.N., Hussain, A. & Kalsotra, B.L. Synthesis and characterization of some oxodiperoxo molybdenum(VI) complexes of Morpholinomethyl urea and related ligands. Russ. J. Inorg. Chem. 51, 724–727 (2006). https://doi.org/10.1134/S003602360605007X
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DOI: https://doi.org/10.1134/S003602360605007X