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Reaction of magnesium oxide and magnesium silicates with ammonium hydrodifluoride

  • Synthesis and Properties of Inorganic Compounds
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Abstract

The reactions of magnesium oxide and magnesium silicates (forsterite and serpentines) with ammonium hydrodifluoride is studied using DTA, X-ray powder diffraction, and IR spectroscopy. The conditions for the formation of intermediate phases are determined. The structure of the silicate mineral does not significantly affect the fluorination.

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Authors and Affiliations

  1. Tananaev Institute of Rare Element and Mineral Chemistry and Technology, Kola Research Center, Russian Academy of Sciences, ul. Fersmana 14, Apatity, Murmansk oblast, 184200, Russia

    D. P. Nesterov, D. V. Makarov & V. T. Kalinnikov

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  1. D. P. Nesterov
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  2. D. V. Makarov
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  3. V. T. Kalinnikov
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Additional information

Original Russian Text © D.P. Nesterov, D.V. Makarov, V.T. Kalinnikov, 2006, published in Zhumal Neorganicheskoi Khimii, 2006, Vol. 51, No. 5, pp. 780–784.

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Nesterov, D.P., Makarov, D.V. & Kalinnikov, V.T. Reaction of magnesium oxide and magnesium silicates with ammonium hydrodifluoride. Russ. J. Inorg. Chem. 51, 712–716 (2006). https://doi.org/10.1134/S0036023606050044

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  • DOI: https://doi.org/10.1134/S0036023606050044

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