Skip to main content
SpringerLink
Log in

Effect of the anionic composition and pH on the dissolution kinetics of chromium(III) oxide and chromium(III) hydroxide oxide in acids

  • Physical Chemistry of Solutions
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

Based on an experimental investigation of the effects of the pH and anionic composition on the dissolution rate of chromium(III) oxide α-Cr2O3 and chromium(III) hydroxide oxide α-CrOOH and subsequent modeling of the process, it is demonstrated that, depending on the pH, the rate-controlling stage of the dissolution is the CrOH2+ or CrHSO 2+4 sobulization.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Sitting, Resources Recovery and Recycling Handbook of Industrial Wastes (Noyes Data Corp., New Jersey, USA, 1975; Metallurgiya, Moscow, 1985).

    Google Scholar 

  2. M. A. Blesa, A. D. Weisz, and P. J. Morando, Coord. Chem. Rev. 196, 31 (2000).

    Article  CAS  Google Scholar 

  3. N. M. Dyatlova, I. G. Gorichev, et al., Koord. Khim. 12 (1), 3 (1986).

    CAS  Google Scholar 

  4. Masahiro Seo, Ryusaburo Furuichi, Go Okamoto, and Norio Sato, Trans. JIM 16, 519 (1975).

    Google Scholar 

  5. Masahiro Seo and Norio Sato, Boshoku Gijutsu 16, 519 (1975).

    Google Scholar 

  6. N. Valverde, Ber. Bunsen-Ges. Phys. Chem. 81 (4), 380 (1977).

    CAS  Google Scholar 

  7. N. Valverde and C. Wagner, Ber. Bunsen-Ges. Phys. Chem. 80 (4), 330 (1976).

    CAS  Google Scholar 

  8. N. Valverde, Ber. Bunsen-Ges. Phys. Chem. 80 (4), 333 (1976).

    CAS  Google Scholar 

  9. N. Valverde, Ber. Bunsen-Ges. Phys. Chem. 92 (4), 1072 (1988).

    CAS  Google Scholar 

  10. T. V. Rode, Oxygen Compounds of Chromium and Chromium Catalysts (Nauka, Moscow, 1962) [in Russian].

    Google Scholar 

  11. Z. Marczenko, Kolorymetryczne oznacznie pierwiasków (Wydawnictwa Naukowo-Techniczne, 1968; Mir, Moscow, 1971).

    Google Scholar 

  12. A. Albert and E. Sergeant, Ionization Constants of Acids and Bases (Wiley, New. York, 1962; Khimiya, Moscow, 1964).

    Google Scholar 

  13. I. G. Gorichev and N. A. Kipriyanov, Zh. Fiz. Khim. 55 (11), 2734 (1981).

    CAS  Google Scholar 

  14. I. G. Gorichev and N. A. Kipriyanov, Usp. Khim. 53 (11), 1790 (1984).

    CAS  Google Scholar 

  15. Reactions in the Solid State, Ed. by M. E. Brown, D. Dollimore, and A. K. Galwey (Elsevier, Amsterdam, 1980; Mir, Moscow, 1983).

    Google Scholar 

  16. B. Delmon, Introduction à la cinétique hétérogène (Technip, Paris, 1969; Mir, Moscow, 1972) [in Russian].

    Google Scholar 

  17. A. A. Bezdenezhnykh, Engineering Techniques for Composing Reaction Rate Equations and Calculating Kinetic Constants (Khimiya, Leningrad, 1973) [in Russian].

    Google Scholar 

  18. I. G. Gorichev, V. V. Batrakov, I. S. Shaplygin, et al., Neorg. Mater. 30 (10), 1203 (1994).

    CAS  Google Scholar 

  19. I. G. Gorichev, V. V. Batrakov, I. S. Shaplygin, et al., Neorg. Mater. 30 (10), 1219 (1994).

    CAS  Google Scholar 

  20. I. G. Gorichev and V. V. Batrakov, Elektrokhimiya 28 (1), 14 (1992).

    CAS  Google Scholar 

  21. A. Blesa, G. Magaz, and J. A. Salfilty, “WeiszA. D,” Solid State Ionics 101–103, 1235 (1997).

    Google Scholar 

  22. S. Kittaka, J. Colloid Interface Sci. 48 (2), 327 (1974).

    CAS  Google Scholar 

  23. J. N. Butler, Ionic Equilibrium: A Mathematical Approach (Addison Wesley, 1964; Khimiya, Leningrad, 1973).

    Google Scholar 

  24. D. W. Fuerstetenau and K. Osseo-Asare, J. Colloid Interface Sci. 118 (2), 524 (1987).

    Google Scholar 

  25. I. G. Gorichev, V. V. Batrakov, and M. V. Dorofeev, Elektrokhimiya 31 (3), 292 (1995).

    Google Scholar 

  26. M. A. Blesa and A. J. G. Maroto, J. Chim. Phys. Phys.-Chim. Biol. 83 (11–12), 757 (1986).

    CAS  Google Scholar 

  27. I. G. Gorichev, M. V. Dorofeev, I. S. Shaplygin, et al., Neorg. Mater. 31 (1), 77 (1995).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Moscow State Pedagogical University, Malaya Pirogovskaya ul. 1, Moscow, 119882, Russia

    I. V. Dorovskikh, I. G. Gorichev & V. V. Batrakov

  2. Russian University of Peoples’ Friendship, ul. Miklukho-Maklaya 6, Moscow, 117198, Russia

    V. V. Kurilkin

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    A. D. Izotov

Authors
  1. I. V. Dorovskikh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. G. Gorichev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. V. Batrakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. V. Kurilkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. D. Izotov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dorovskikh, I.V., Gorichev, I.G., Batrakov, V.V. et al. Effect of the anionic composition and pH on the dissolution kinetics of chromium(III) oxide and chromium(III) hydroxide oxide in acids. Russ. J. Inorg. Chem. 51, 143–151 (2006). https://doi.org/10.1134/S0036023606010220

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023606010220

Keywords

Search

Navigation