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Synthesis, structural characterization, and antifungal activity of Schiff bases and their transition metal mixed-ligand complexes

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Abstract

Mixed-ligand complexes of Mn(II), Co(II), Ni(II), Cu(II), Zn(II), and Cd(II) have been prepared with biologically active Schiff bases, viz. potassium salt of o-hydroxyacetophenoneglycine [KHL] and bis(benzylidene)ethylenediamine [A1] or thiophene-o-carboxaldene-p-toluidine [A2]. The synthesized mixed-ligand complexes have been characterized on the basis of elemental analysis, thermogravimetric analysis, magnetic measurements, and electronic and infrared spectra. The mixed-ligand complexes show higher antifungal activity as compared to the free ligands, metal salts, and the control (dimethylsulfoxide) but moderate activity as compared to the standard fungicides (bavistin and emcarb).

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References

  1. A. Saxena, J. K. Koacher, and J. P. Tondon, Inorg. Nucl. Chem. Lett. 17, 229 (1981).

    Article  CAS  Google Scholar 

  2. P. K. Panchal, D. H. Patel, and M. N. Patel, Synth. React. Inorg. Met.-Org. Chem. 34, 1223 (2004).

    CAS  Google Scholar 

  3. A. I. Vogel, Textbook of Practical Organic Chemistry, 5th ed. (Longman, London, 1989).

    Google Scholar 

  4. P. P. Dholakiya and M. N. Patel, Synth. React. Inorg. Met.-Org. Chem. 32, 819 (2002).

    CAS  Google Scholar 

  5. A. I. Vogel, Textbook of Practical Organic Chemistry, 3rd ed. (Longman, London, 1975).

    Google Scholar 

  6. B. R. Pandya, S. K. Menon, and Y. K. Agrawal, Synth. React. Inorg. Met.-Org. Chem. 34, 1291 (2004).

    Article  CAS  Google Scholar 

  7. M. Tumer, B. Erdogan, H. Koksal, et al., Synth. React. Inorg. Met.-Org. Chem. 288, 529 (1998).

    Google Scholar 

  8. E. Tas, A. Cukurovali, and M. Kaya, J. Coord. Chem. 44, 109 (1998).

    CAS  Google Scholar 

  9. R. V. Singh, J. P. Tondon, Synth. React. Inorg. Met.-Org. Chem. 9, 121 (1979).

    CAS  Google Scholar 

  10. N. K. Singh, S. K. Kushawaha, A. Srivastava, and A. Sodhi, Synth. React. Inorg. Met.-Org. Chem. 32, 1743 (2002).

    CAS  Google Scholar 

  11. S. K. Sahni, S. K. Sangal, S. P. Gupta, and V. B. Rana, J. Inorg. Nucl. Chem. 39, 1098 (1977).

    Article  CAS  Google Scholar 

  12. F. A. El-Saied, M. I. Ayad, and S. A. Aly, Trans. Met. Chem. 18, 279 (1993).

    CAS  Google Scholar 

  13. S. Chandra, N. Gupta, and L. K. Gupta, Synth. React. Inorg. Met.-Org. Chem. 34, 919 (2004).

    CAS  Google Scholar 

  14. K. H. Mostaga, M. H. Refat, and A. A. Mohamed, Monatsh. Chem. 122, 829 (1991).

    Google Scholar 

  15. R. Carbello, A. Cartineiras, W. Hiller, and J. Strahle, Polyhedron 12, 1083 (1993).

    Google Scholar 

  16. G. Wilkinson and F. A. Cotton, Advanced Inorganic Chemistry, 5th ed. (Wiley, New York, 1988).

    Google Scholar 

  17. H. Koksal, M. Dolaz, M. Tumer, and S. Serin, Synth. React. Inorg. Met.-Org. Chem. 31, 1141 (2001).

    CAS  Google Scholar 

  18. P. S. Patel, R. M. Rah, and M. M. Patel, Indian J. Chem. Soc. 32, 597 (1993).

    Google Scholar 

  19. A. B. P. Lever, “Electronic Spectra of d n Ions,” in Inorganic Electronic Spectroscopy, 2nd ed. (Elsevier, Amsterdam, 1984).

    Google Scholar 

  20. Y. Gok and S. Serin, Synth. React. Inorg. Met.-Org. Chem. 18, 975 (1988).

    CAS  Google Scholar 

  21. B. B. Kaul and K. B. Pandya, J. Inorg. Nucl. Chem. 40, 1035 (1978).

    CAS  Google Scholar 

  22. A. El-Dissouky, A. M. Hindawey, and A. Abdel-Salam, Inorg. Chem. Acta 118, 109 (1986).

    Article  CAS  Google Scholar 

  23. R. M. Atlas, Manual of Industrial Microbiology and Biotechnology (ASM Press, Washington DC, 1999).

    Google Scholar 

  24. J. B. Chauhan, R. B. Subramanian, and P. K. Sanyal, Indian J. Environ. Toxicol. 12, 22 (2002).

    Google Scholar 

  25. B. G. Tweedy, Phytopatology 55, 910 (1964).

    Google Scholar 

  26. E. Konig, “The Nephelauxetic Effect,” in Structure and Bonding (Springer Verlag, Berlin/Heidelberg/New York, 1971).

    Google Scholar 

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Parekh, H.M., Mehta, S.R. & Patel, M.N. Synthesis, structural characterization, and antifungal activity of Schiff bases and their transition metal mixed-ligand complexes. Russ. J. Inorg. Chem. 51, 67–72 (2006). https://doi.org/10.1134/S003602360601013X

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  • DOI: https://doi.org/10.1134/S003602360601013X

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