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Synthesis and structure of Mercury 8-selenolquinolinate Hg(C9H6NSe)2: Crystal-chemical comparison of mercury 8-selenol-, 8-mercapto-, and 8-hydroxyquinolinates

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Abstract

Mercury 8-selenolquinolinate was synthesized and studied by X-ray diffraction. In neutral Hg(C9H6NSe)2, 8-selenolquinoline is a bidentate (S,N) ligand. The coordination polyhedron of mercury is a distorted tetrahedron or a seesaw (2Se + 2N). The bond lengths are as follows: Hg-Se, 2.4599(9) and 2.4606(9) Å; Hg...N, 2.497(6) and 2.513(6) Å. The SeHgSe bond angle is 166.07(3)°. Mercury 8-selenolquinolinate belongs to the class of chelates in which the five-membered chelate rings-Hg-Se-C-C-N-contain a donor selenium atom. The structures and the Hg-Se, Hg-S, Hg-O, and Hg-N bonds in mercury 8-selenol-, 8-mercapto-, and 8-hydroxyquinolinates were analyzed.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Riga Technical University, Riga, Latvia

    E. Ya. Silin’, Ya. V. Ashaks, L. Ya. Pech, D. E. Zaruma & Yu. A. Bankovskii

  2. Karpov Research Institute of Physical Chemistry, ul. Vorontsovo pole 10, Moscow, 103064, Russia

    V. K. Bel’skii & A. I. Stash

Authors
  1. E. Ya. Silin’
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  2. V. K. Bel’skii
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  3. A. I. Stash
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  4. Ya. V. Ashaks
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  5. L. Ya. Pech
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  6. D. E. Zaruma
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  7. Yu. A. Bankovskii
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Silin’, E.Y., Bel’skii, V.K., Stash, A.I. et al. Synthesis and structure of Mercury 8-selenolquinolinate Hg(C9H6NSe)2: Crystal-chemical comparison of mercury 8-selenol-, 8-mercapto-, and 8-hydroxyquinolinates. Russ. J. Inorg. Chem. 51, 57–63 (2006). https://doi.org/10.1134/S0036023606010116

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  • DOI: https://doi.org/10.1134/S0036023606010116

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