Skip to main content
SpringerLink
Log in

Kinetics of solid-state synthesis and properties of lead-containing niobate pyrochlores

  • Synthesis and Properties of Inorganic Compounds
  • Published:
Russian Journal of Inorganic Chemistry Aims and scope Submit manuscript

Abstract

The main features of the synthesis of (Pb1-x Srx)2Nb2O7 and (Pb1-x Bax)2Nb2O7 pyrochlore solid solutions were determined using isothermal thermogravimetry in tandem with formal-kinetic analysis. The stability and electron-transport properties of the triple niobates were studied, which allowed us to test them as electrode-active materials for membranes in ion-selective electrodes (ISEs).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. L. Podkorytov, S. A. Shtin, V. M. Zhukovskii, et al., Proceedings of the 5th International Conference “Fundamental Issues of Solid-State Ionics,” Chernogolovka (Russia), 2000 (Chernogolovka, 2000), p. 150 [in Russian].

  2. E. V. Sokolova, S. A. Shtin, A. L. Podkorytov, and V. M. Zhukovskii, Abstracts of Papers of the All-Russia Conference “Topics in Analytical Chemistry,” Moscow, 2002 (Moscow, 2002), p. 158 [in Russian].

  3. E. V. Sokolova, S. A. Shtin, and A. L. Podkorytov, Proceedings of the 5th All-Union Conference on the Environmental Analysis “Ekoanalitika-2003,” St. Petersburg, 2003 (St. Petersburg, 2003), p. 272 [in Russian].

  4. B. Delmon, Introduction à la cinétique hétérogéne (Technip, Paris, 1969; Mir, Moscow, 1972).

    Google Scholar 

  5. S. R. Kudakaeva, A. L. Podkorytov, E. V. Sokolova, and S. A. Shtin, Zh. Neorg. Khim. 50 (6), 945 (2005) [Russ. J. Inorg. Chem. 50 (6), 866 (2005)].

    CAS  Google Scholar 

  6. A. P. Kreshkov, Hydrogen Sulfide-free Qualitative Semimicroanalysis (Moscow, 1979) [in Russian].

  7. A. Ya. Neiman, I. P. Zapasskaya, A. L. Podkorytov, and V. M. Zhukovskii, Zh. Neorg. Khim. 28 (9), 2220 (1983).

    CAS  Google Scholar 

  8. Chemical Encyclopedia, Ed. by I. L. Knunyants (Sov. Entsiklopediya, Moscow, 1988), Vol. 4 [in Russian].

    Google Scholar 

  9. P. P. Budnikov and A. M. Ginstling, Reactions in Mixtures of Solid Substances (Stroiizdat, Moscow, 1971) [in Russian].

    Google Scholar 

  10. V. N. Chebotin and M. V. Perfil’ev, Electrochemistry of Solid Electrolytes (Khimiya, Moscow, 1978) [in Russian].

    Google Scholar 

  11. V. N. Chebotin, Physical Chemistry of the Solid State (Khimiya, Moscow, 1982) [in Russian].

    Google Scholar 

  12. S. A. Shtin, Candidate’s Dissertation in Chemistry (Yekaterinburg, 2002).

  13. J. Koryta and K. Stulik, Ion-Selective Electrodes (Academia, Prague, 1984; Mir, Moscow, 1989).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ural State University, pr. Lenina 51, Yekaterinburg, 620083, Russia

    A. L. Podkorytov, S. R. Kudakaeva, E. V. Sokolova, S. A. Shtin & D. N. Ashikhmin

Authors
  1. A. L. Podkorytov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. R. Kudakaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Sokolova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. A. Shtin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. D. N. Ashikhmin
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Podkorytov, A.L., Kudakaeva, S.R., Sokolova, E.V. et al. Kinetics of solid-state synthesis and properties of lead-containing niobate pyrochlores. Russ. J. Inorg. Chem. 51, 46–50 (2006). https://doi.org/10.1134/S0036023606010098

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036023606010098

Keywords

Search

Navigation