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Synthesis and complex investigation of potassium ammonium hexafluorozirconates: I. Synthesis and X-ray diffraction study of K2-x (NH4)xZrF6 (0 < x < 2) crystals

  • Synthesis and Properties of Inorganic Compounds
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Abstract

The synthesis and X-ray diffraction study of compounds K2-x (NH4)xZrF6 (0 < x < 2) were carried out. In all crystals of mixed composition, potassium cations are isomorphously replaced by ammonium cations. The compounds with x < 0.5 are isostructural to K2ZrF6 and those with x > 1.5, to (NH4)2ZrF6. At 0.5 < x < 1.5, the structures are built of linear polymeric chains formed by edge-sharing Zr dodecahedra. The distribution of potassium and ammonium cations over the cationic positions was considered.

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References

  1. V. Ya. Kavun, A. V. Gerasimenko, V. I. Sergienko, et al., Zh. Prikl. Khim. 75 (6), 966 (2000).

    Google Scholar 

  2. V. Ya. Kavun, V. I. Sergienko, and T. F. Antokhina, Zh. Strukt.Khim. 36 (4), 696 (1995).

    Google Scholar 

  3. D. Yu. Popov, V. Ya. Kavun, A. V. Gerasimenko, et al., Zh. Neorg. Khim. 44 (1), 103 (1999) [Russ. J. Inorg. Chem. 44 (1), 97 (1999)].

    CAS  Google Scholar 

  4. D. Yu. Popov, V. Ya. Kavun, A. V. Gerasimenko, et al., Koord. Khim. 25 (10), 75 (1999).

    Google Scholar 

  5. V. Ya. Kavun, V. I. Sergienko, and N. F. Uvarov, Zh. Strukt. Khim. 44 (5), 865 (2003).

    Google Scholar 

  6. V. R. Hoppe and D. Mehlorn, Z. Anorg. Allg. Chem. 425, 200 (1976).

    Article  CAS  Google Scholar 

  7. V. Ya. Kavun, V. I. Sergienko, B. N. Chernyshov, et al., Zh. Neorg. Khim. 36 (4), 1004 (1991).

    CAS  Google Scholar 

  8. I. V. Tananaev and L. S. Guzeeva, Izv. Akad. Nauk SSSR, Ser. Neorg. Mater. 4 (2), 207 (1968).

    CAS  Google Scholar 

  9. Bruker (1998). SMART and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System, Bruker AXS, Inc., Madison, Wisconsin, USA.

    Google Scholar 

  10. Bruker (1998). SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data, Bruker AXS, Inc., Madison, Wisconsin, USA.

    Google Scholar 

  11. M. A. Porai-Koshits and L. A. Aslanov, Zh. Strukt. Khim. 13 (2), 266 (1972).

    CAS  Google Scholar 

  12. R. K. Rastsvetaeva, R. A. Tamazyan, and D. Yu. Pushcharovskii, Kristallografiya 39 (6), 994 (1994).

    CAS  Google Scholar 

  13. B. V. Bukvetskii, A. V. Gerasimenko, and R. L. Davidovich, Koord. Khim. 17 (1), 35 (1991).

    CAS  Google Scholar 

  14. V. A. Blatov, A. P. Shevchenko, and V. N. Serezhkin, J. Appl. Crystallogr. 33 (4), 1193 (2000).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    A. V. Gerasimenko, I. A. Tkachenko, V. Ya. Kavun, N. A. Didenko & V. I. Sergienko

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  1. A. V. Gerasimenko
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  2. I. A. Tkachenko
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  3. V. Ya. Kavun
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  4. N. A. Didenko
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  5. V. I. Sergienko
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Gerasimenko, A.V., Tkachenko, I.A., Kavun, V.Y. et al. Synthesis and complex investigation of potassium ammonium hexafluorozirconates: I. Synthesis and X-ray diffraction study of K2-x (NH4)xZrF6 (0 < x < 2) crystals. Russ. J. Inorg. Chem. 51, 9–22 (2006). https://doi.org/10.1134/S0036023606010037

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  • DOI: https://doi.org/10.1134/S0036023606010037

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