Abstract
Scanning vibrating capacitor (Kelvin probe) and electrochemical impedance spectroscopy are used in electrochemical monitoring of the atmospheric corrosion of zinc. The effect of the corrosion product layer on the surface potential and capacitance is studied. Upon the local application of NaCl, the spatial separation of the cathodic and anodic reactions was noticed in the profiles of the electrode potential and chemical composition of the corrosion products (infrared microscopy). The effect of corrosion inhibitors and activators on the electrochemical atmospheric corrosion of zinc is studied.
Similar content being viewed by others
References
Rozenfel’d, I.L., Atmosphernaya korroziya (Atmospheric Corrosion), Moscow: Izd. Akad. Nauk SSSR, 1960.
Stratmann, M. and Streckel, H., Corros. Sci., 1990, vol. 30, p. 681.
Nazarov, A. and Thierry, D., J. Electrochem. Soc., 1998, vol. 145, p. L39.
Yadav, A.P., Nishikata, A., and Tsuru, T., Corros. Sci., 2004, vol. 46, p. 168.
Nazarov, A. and Thierry, D., Electrochim. Acta, 2004, vol. 49, nos. 17–18, p. 2717.
Nazarov, A. and Thierry, D., Proc. Eurocorr-98, 1998, Utrecht.
Nazarov, A. and Thierry D., Proc. Eurocorr-00, 2000, London.
Neufeld, A.K., Cole, I.S., Bond, A.M., and Furman, S.A., Corros. Sci., 2002, vol. 44, p. 555.
Nazarov, A.P. and Thierry, D., Zashch. Met., 2004, vol. 40, no. 4, p. 421.
Le Bozec, N., Persson, D., Nazarov, A., and Thierry, D., J. Electrochem. Soc., 2002, vol. 149, no. 9, p. B403.
Huang, S.-M., Yee, S., Atanasoski, R.T., et al., J. Electrochem. Soc., 1991, vol. 138, no. 11, p. L63.
Zangwill, A., Physics at Surfaces, Cambridge: Cambridge Univ. Press, 1988.
Yadav, A.P., Suzuki, F., Nishikata, A., and Tsuru, T., Electrochim. Acta, 2004, vol. 49, p. 2725.
Nazarov, A., Thierry, D., Prosek, T., and Le Bozec, N., J. Electrochem. Soc., 2005, vol. 152, no. 7, p. B220.
Mikhailovskii, Yu.N., Zasul’skaya, M.N., Nazarov, A.P., et al., Zashch. Met., 1985, vol. 21, p. 353.
Author information
Authors and Affiliations
Additional information
Original Russian Text © A.P. Nazarov, D. Thierry, 2006, published in Zashchita Metallov, 2006, Vol. 42, No. 5, pp. 478–492.
Rights and permissions
About this article
Cite this article
Nazarov, A.P., Thierry, D. Probing the atmospheric corrosion of metals. Zinc. Prot Met 42, 437–451 (2006). https://doi.org/10.1134/S003317320605002X
Received:
Issue Date:
DOI: https://doi.org/10.1134/S003317320605002X