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Kinetics of the Cu2O chemical decomposition during the copper electrochemical oxidation in the sulfuric-acid-based electrolyte systems

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Abstract

Electrochemical copper oxidation in sulfuric acid aqueous solutions and sulfate electrolytes thickened with the silicon-dioxide powder is studied potentiodynamically. Based on the current theoretical concepts, the polarization-rate dependences of the anodic current density maximum is analyzed. It is shown that these dependences can be adequately described using a porous-layer resistance model that takes into account chemical decomposition of the passivating Cu2O film formed via electrochemical mechanism. The film decomposition rate constants are calculated for the studied electrolytic systems at different temperatures.

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References

  1. Moreira, A.H., Benedetti, A.V., Cabot, P.L., and Sumodjo, T.A., Electrochim. Acta, 1993, vol. 38, no. 7, p. 981.

    Article  CAS  Google Scholar 

  2. Kinoshita, K., Landolt, D., Muller, R.M., and Gibais, C.W., J. Electrochem. Soc., 1970, vol. 117, no. 10, p. 1246.

    CAS  Google Scholar 

  3. Grishina, E.P., Udalova, A.M., and Rumyantsev, E.M., Elektrokhimiya, 2002, vol. 38, no. 9, p. 1155.

    Google Scholar 

  4. Spravochnik po elektrokhimii (A Handbook of Electrochemistry), Sukhotin, A.M., Ed., Leningrad: Khimiya, 1981.

    Google Scholar 

  5. Calandra, A.J., de Tacconi, R.N., Pereiro, R., and Arvia, A.J., Electrochim. Acta, 1974, vol. 19, no. 12, p. 901.

    Article  CAS  Google Scholar 

  6. Khobotova, E.B., Zh. Prikl. Khim., 1992, vol. 65, no. 8, p. 1761.

    CAS  Google Scholar 

  7. Noskov, A.V. and Grishina, E.P., Zashch. Met., 2005, vol. 41, no. 2, 158.

    Google Scholar 

  8. Remi, H., Treatise on Inorganic Chemistry, New York: Elsevier, 1956.

    Google Scholar 

  9. Lopatin, B.A., Teoreticheskie osnovy elektrokhimicheskikh metodov analiza (The Theoretical Foundations for the Electrochemical Methods of Analysis), Moscow: Vyssh. Shkola, 1975.

    Google Scholar 

  10. Rotinyan, A.L., Tikhonov, K.I., and Shoshina, I.A., Teoreticheskaya elektrokhimiya (The Theoretical Electrochemistry), Leningrad: Khimiya, 1981.

    Google Scholar 

  11. Charykov, A.K., Matematicheskaya obrabotka materialov khimicheskogo analiza (Mathematical Processing of the Chemical Analysis Data), Leningrad: Khimiya, 1984.

    Google Scholar 

  12. Fiziko-khimicheskie svoistva okislov (Physicochemical Properties of Oxides), Samsonov, G.V., Ed., Moscow: Metallurgiya, 1978.

    Google Scholar 

  13. Grishina, E.P. and Rumyantsev, E.M., Elektron. Obrab. Mater., 1999, no. 3, p. 29.

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Authors and Affiliations

  1. Institute of Solutions Chemistry, Russian Academy of Sciences, ul. Akademicheskaya 1, Ivanovo, 153045, Russia

    A. V. Noskov, E. P. Grishina & A. M. Pimenova

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  1. A. V. Noskov
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  2. E. P. Grishina
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  3. A. M. Pimenova
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Original Russian Text © A.V. Noskov, E.P. Grishina, A.M. Pimenova, 2006, published in Zashchita Metallov, 2006, Vol. 42, No. 2, pp. 163–167.

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Noskov, A.V., Grishina, E.P. & Pimenova, A.M. Kinetics of the Cu2O chemical decomposition during the copper electrochemical oxidation in the sulfuric-acid-based electrolyte systems. Prot Met 42, 149–152 (2006). https://doi.org/10.1134/S0033173206020081

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