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A-Site Order-Disorder Evolution in Double Manganites RBaMn2O6 (R = Pr, Nd)

  • ELECTRICAL AND MAGNETIC PROPERTIES
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Abstract

Structural, magnetic and optical properties of double manganites PrBaMn2O6 and NdBaMn2O6 are studied depending on the degree of ordering in the A-position. It is shown that, annealing induced disordering goes in an initial stage throw formation of a two-phase state: a phase with a high A-site ordering with TC ∼ 280–300 K and a phase with a low ordering of ~30% with significantly lower TC coexist. In partially ordered PrBaMn2O6 samples there are metal-insulator transitions near TC of the each coexisting phases. In partially ordered NdBaMn2O6 in a highly A-site ordered high-temperature phase, there is no metal-insulator transition due to the destruction of the channels for metallic conductivity formed by the ordering of the x2‒y2 orbitals. If a metal-insulator transition takes place, the application of a magnetic field leads to the effect of magnetotransmission near TC, which is associated with a change in the concentration of delocalized charge carriers.

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Funding

The work was supported by the Russian Science Foundation, grant no. 22-22-00507.

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Authors and Affiliations

  1. M.N. Miheev Institute of Metal Physics, Ural Branch of Russian Academy of Sciences, 620108, Ekaterinburg, Russia

    E. V. Mostovshchikova

  2. Institute of Metallurgy, Ural Branch of Russian Academy of Sciences, 620016, Ekaterinburg, Russia

    E. V. Sterkhov, S. V. Pryanichnikov, L. B. Vedmid’ & S. G. Titova

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  1. E. V. Mostovshchikova
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Correspondence to E. V. Mostovshchikova.

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Mostovshchikova, E.V., Sterkhov, E.V., Pryanichnikov, S.V. et al. A-Site Order-Disorder Evolution in Double Manganites RBaMn2O6 (R = Pr, Nd). Phys. Metals Metallogr. 124, 1703–1715 (2023). https://doi.org/10.1134/S0031918X23602421

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