Skip to main content
Log in

Magnetic Phase Transitions in the Fe1 – xZnxCr2S4 Alloy: Method of Random Fields of Exchange Interaction

  • ELECTRICAL AND MAGNETIC PROPERTIES
  • Published:
Physics of Metals and Metallography Aims and scope Submit manuscript

Abstract

The magnetic properties of the Fe1 – xZnxCr2S4 alloy were studied using the method of random fields of exchange interaction. The critical concentrations, at which a transition from a ferrimagnetic state to a spin-glass state (\(x = 0.66\)) with a subsequent transition to an antiferromagnetic state (\(x = 0.99\)), are observed. A magnetic phase diagram, which compares the calculation results with the experiment, was constructed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

REFERENCES

  1. F. J. Berry, T. V. Dmitrieva, N. S. Ovanesyan, I. S. Lyu-butin, M. F. Thomas, V. A. Sarkisyan, X. Ren, T. G. Aminov, G. G. Shabunina, V. Rudenko, A. Vorotynov, and Yu. L. Dubinskaya, “Magnetic order in FeCr2S4-type chalcogenide spinels,” J. Phys.: Condens. Matter 19, 266204 (2007). https://doi.org/10.1088/0953-8984/19/26/266204

    Article  CAS  Google Scholar 

  2. A. P. Ramirez, R. J. Cava, and J. Krajewski, “Colossal magnetoresistance in Cr-based chalcogenide spinels,” Nature 386, 156–159 (1997). https://doi.org/10.1038/386156a0

    Article  CAS  Google Scholar 

  3. V. Fritsch, J. Deisenhofer, R. Fichtl, J. Hemberger, H.‑A. Krug Von Nidda, M. Mücksch, M. Nicklas, D. Samusi, J. D. Thompson, R. Tidecks, V. Tsurkan, and A. Loidl, “Anisotropic colossal magnetoresistance effects in Fe1 – xCuxCr2S4,” Phys. Rev. B 67, 144419 (2003). https://doi.org/10.1103/physrevb.67.144419

    Article  Google Scholar 

  4. J. Hemberger, P. Lunkenheimer, R. Fichtl, H. Krug Von Nidda, V. Tsurkan, and A. Loidl, “Relaxor ferroelectricity and colossal magnetocapacitive coupling in ferromagnetic CdCr2S4,” Nature 434, 364–367 (2005). https://doi.org/10.1038/nature03348

    Article  CAS  Google Scholar 

  5. Y. Yamasaki, S. Miyasaka, Y. Kaneko, J. He, T. Arima, and Y. Tokura, “Magnetic reversal of the ferroelectric polarization in a multiferroic spinel oxide,” Phys. Rev. Lett. 96 (20), 207204 (2006). https://doi.org/10.1103/PhysRevLett.96.207204

    Article  CAS  Google Scholar 

  6. S. Weber, P. Lunkenheimer, R. Fichtl, J. Hemberger, V. Tsurkan, and A. Loidl, “Colossal magnetocapacitance and colossal magnetoresistance in HgCr2S4,” Phys. Rev. Lett. 96, 157202 (2006). https://doi.org/10.1103/physrevlett.96.157202

    Article  CAS  Google Scholar 

  7. M. Mertinat, V. Tsurkan, D. Samusi, R. Tidecks, and F. Haider, “Low-temperature structural transition in FeCr2S4,” Phys. Rev. B 71, 100408 (2005). https://doi.org/10.1103/physrevb.71.100408

    Article  Google Scholar 

  8. G. M. Kalvius, A. Krimmel, O. Hartmann, R. Wäppling, F. E. Wagner, F. J. Litterst, V. Tsurkan, and A. Loidl, “Low temperature incommensurately modulated and noncollinear spin structure in FeCr2S4,” J. Phys.: Condens. Matter 22, 052205 (2010). https://doi.org/10.1088/0953-8984/22/5/052205

    Article  CAS  Google Scholar 

  9. K.-Y. Choi, P. Lemmens, P. Scheib, V. Gnezdilov, Yu. G. Pashkevich, J. Hemberger, A. Loidl, and V. Tsurkan, “Anomalous electronic, phonon, and spin excitations in the chalcogenide spinel FeCr2S4,” J. Phys.: Condens. Matter 19, 145260 (2007). https://doi.org/10.1088/0953-8984/19/14/145260

    Article  CAS  Google Scholar 

  10. T. G. Aminov, D. I. Kirdyankin, G. G. Shabunina, and V. M. Novotortsev, “The study of magnetic phase diagram of Fe1 − xZnxCr2S4 solid solutions,” J. Solid State Chem. 204, 123–127 (2013). https://doi.org/10.1016/j.jssc.2013.05.025

    Article  CAS  Google Scholar 

  11. T. G. Aminov, D. I. Kirdyankin, G. G. Shabunina, and V. M. Novotortsev, “The study of magnetic phase diagram of Fe1 – xZnxCr2S4 solid solutions,” J. Solid State Chem. 204, 123–127 (2013). https://doi.org/10.1016/j.jssc.2013.05.025

    Article  CAS  Google Scholar 

  12. V. Belokon and S. Semkin, “Random field method in the theory of ferromagnetism of binary alloys,” J. Exp. Theor. Phys. 104, 3784–3791 (1993).

    CAS  Google Scholar 

  13. V. I. Belokon and K. V. Nefedev, “Distribution function for random interaction fields in disordered magnets: Spin and macrospin glass,” J. Exp. Theor. Phys. 93, 136–142 (2001). https://doi.org/10.1134/1.1391530

    Article  CAS  Google Scholar 

  14. V. I. Belokon, O. I. Dyachenko, R. V. Lapenkov, and E. V. Chibiriak, “Variety of types of magnetic ordering: The method of random exchange interaction fields,” Phys. Met. Metallogr. 121, 729–732 (2020). https://doi.org/10.1134/s0031918x20060034

    Article  CAS  Google Scholar 

  15. V. Belokon, A. Trofimov, and O. Dyachenko, “Oguchi’s method and random interaction fields’ method: Investigation of properties of ferromagnetic materials,” J. Magn. Magn. Mater. 471, 501–503 (2019). https://doi.org/10.1016/j.jmmm.2018.09.065

    Article  CAS  Google Scholar 

  16. L. Lin, H. X. Zhu, X. M. Jiang, K. F. Wang, S. Dong, Z. B. Yan, Z. R. Yang, J. G. Wan, and J.-M. Liu, “Coupled ferroelectric polarization and magnetization in spinel FeCr2S4,” Sci. Rep. 4, 6530 (2014). https://doi.org/10.1038/srep06530

    Article  CAS  Google Scholar 

  17. V. I. Belokon, O. I. Dyachenko, and R. V. Lapenkov, “The magnetic susceptibility of alloys below the percolation threshold,” Phys. Met. Metallogr. 124, 22–26 (2023). https://doi.org/10.1134/s0031918x22601755

    Article  CAS  Google Scholar 

  18. S. V. Vonsovskii, Magnetism (Nauka, Moscow, 1984).

    Google Scholar 

Download references

Funding

The work was supported by the program of the President of the Russian Federation for state support of leading scientific schools of the Russian Federation, grant no. NSh-2559.2022.1.2.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to O. I. Dyachenko.

Ethics declarations

The authors of this work declare that they have no conflicts of interest.

Additional information

Translated by A. Ivanov

Publisher’s Note.

Pleiades Publishing remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Belokon’, V.I., Dyachenko, O.I. Magnetic Phase Transitions in the Fe1 – xZnxCr2S4 Alloy: Method of Random Fields of Exchange Interaction. Phys. Metals Metallogr. 124, 955–960 (2023). https://doi.org/10.1134/S0031918X23601701

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0031918X23601701

Keywords:

Navigation