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Effect of Ni on the Contributions of Superplastic Deformation Mechanisms in an Al–Zn–Mg–Cr Alloy

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Abstract

The influence of nickel on superplasticity characteristics, microstructure evolution and the contribution of acting superplastic deformation mechanisms in the Al–Zn–Mg–Cr based alloys has been studied. In the Al–Zn–Mg–Cr alloy, dispersoids with an average size of 140 nm containing aluminum, chromium, magnesium, and a small amount of zinc are precipitated. In the Al–Zn–Mg–Cr–Ni alloy, additionally an Al3Ni phase has formed. Nickel aluminide provides a more homogeneous and stable grain structure at elevated annealing temperatures and during superplastic deformation at 440°C. An alloying with Ni reduced the average grain size from 7.7 to 7.3 μm before deformation and from 10 to 8.6 μm after straining to 0.69. An increased dislocation density has been found near the Al3Ni particles after deformation. At comparable values of the strain rate sensitivity coefficient (m ≈ 0.6), the presence of Al3Ni particles results in a higher contribution of GBS, and a lower contribution of intragranular dislocation slip, as compared to the alloy without these particles. The alloying with Ni provided a more equiaxed fine-grained structure and an increase in elongations-to-failure.

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REFERENCES

  1. J. J. Blandin, “Superplasticity of metallic alloys: Some current findings and open questions,” Mater. Sci. Forum 838839, 13–22 (2016). https://doi.org/10.4028/www.scientific.net/msf.838-839.13

  2. T. G. Langdon, “Seventy-five years of superplasticity: Historic developments and new opportunities,” J. Mater. Sci. 44, 5998–6010 (2009). https://doi.org/10.1007/s10853-009-3780-5

    Article  CAS  Google Scholar 

  3. X.-G. Wang, Q.-Sh. Li, R.-R. Wu, X.-Yu. Zhang, and L. Ma, “A review on superplastic formation behavior of Al alloys,” Adv. Mater. Sci. Eng. 2018, 7606140 (2018). https://doi.org/10.1155/2018/7606140

    Article  CAS  Google Scholar 

  4. T. G. Langdon, “Twenty-five years of ultrafine-grained materials: Achieving exceptional properties through grain refinement,” Acta Mater. 61, 7035–7059 (2013). https://doi.org/10.1016/j.actamat.2013.08.018

    Article  CAS  Google Scholar 

  5. I. I. Novikov and V. K. Portnoj, Superplastizität von Legierungen (Springer, Vienna, 1985). https://doi.org/10.1007/978-3-7091-9521-5

    Book  Google Scholar 

  6. H. Jin, “Optimization of aluminum alloy AA5083 for superplastic and quick plastic forming,” Metall. Mater. Trans. A 50, 3868–3890 (2019). https://doi.org/10.1007/s11661-019-05305-x

    Article  CAS  Google Scholar 

  7. A. H. Chokshi, “Grain boundary processes in strengthening, weakening, and superplasticity,” Adv. Eng. Mater. 22, 1900748 (2020). https://doi.org/10.1002/adem.201900748

    Article  CAS  Google Scholar 

  8. T. Wang, J. Hu, L.-X. Du, G.-Sh. Sun, and R. D. K. Misra, “Strain rate and temperature dependence of low temperature superplastic deformation in a nanostructured microalloyed steel,” Mater. Lett. 243, 165–168 (2019). https://doi.org/10.1016/j.matlet.2019.02.044

    Article  CAS  Google Scholar 

  9. G. Giuliano, Superplastic Forming of Advanced Metallic Materials (Woodhead Publishing, 2011). https://doi.org/10.1533/9780857092779

    Book  Google Scholar 

  10. D. Y. Hwang, K. Kwon, D. H. Shin, K. T. Park, Yo. G. Ko, and C. S. Lee, “Superplastic behavior of ultrafine grained Al alloys fabricated by severe plastic deformation,” Key Eng. Mater. 345346, 597–600 (2007). https://doi.org/10.4028/www.scientific.net/kem.345-346.597

  11. V. P. Poida, D. E. Pedun, V. V. Bryukhovetskii, A. V. Poida, R. V. Sukhov, A. L. Samsonik, and V. V. Litvinenko, “Structural changes during superplastic deformation of high-strength alloy 1933 of the Al–Mg–Zn–Cu–Zr system,” Phys. Met. Metallogr. 114, 779–788 (2013). https://doi.org/10.1134/S0031918X13070090

    Article  Google Scholar 

  12. A. D. Kotov, A. V. Mikhaylovskaya, and V. K. Portnoy, “Effect of the solid-solution composition on the superplasticity characteristics of Al–Zn–Mg–Cu–Ni–Zr alloys,” Phys. Met. Metallogr. 115, 730–735 (2014). https://doi.org/10.1134/S0031918X14070047

    Article  Google Scholar 

  13. A. D. Kotov, A. V. Mikhailovskaya, and V. K. Portnoy, “Superplasticity of alloy Al–11% Zn–3% Mg–0.8% Cu–0.3% Zr with Fe and Ni additives,” Met. Sci. Heat Treat. 55, 364–367 (2013). https://doi.org/10.1007/s11041-013-9636-2

    Article  CAS  Google Scholar 

  14. O. A. Yakovtseva, A. D. Kotov, M. N. Sitkina, A. V. Irzhak, and A. V. Mikhaylovskaya, “Mechanisms of superplastic high-rate deformation in the Al–Mg–Zn–Fe–Ni–Zr–Sc alloy,” Phys. Met. Metallogr. 120, 1014–1020 (2019). https://doi.org/10.1134/S0031918X19100156

    Article  CAS  Google Scholar 

  15. O. A. Yakovtseva, M. N. Sitkina, A. D. Kotov, O. V. Rofman, and A. V. Mikhaylovskaya, “Experimental study of the superplastic deformation mechanisms of high-strength aluminum-based alloy,” Mater. Sci. Eng., A 788, 139639 (2020). https://doi.org/10.1016/j.msea.2020.139639

    Article  CAS  Google Scholar 

  16. O. Yakovtseva, A. Tomas, and A. Mikhaylovskaya, “Surface and internal structural markers for studying grain boundary sliding and grain rotation,” Mater. Lett. 268, 127569 (2020). https://doi.org/10.1016/j.matlet.2020.127569

    Article  CAS  Google Scholar 

  17. A. V. Mikhaylovskaya, O. A. Yakovtseva, M. N. Sitkina, A. D. Kotov, A. V. Irzhak, S. V. Krymskiy, and V. K. Portnoy, “Comparison between superplastic deformation mechanisms at primary and steady stages of the fine grain AA7475 aluminium alloy,” Mater. Sci. Eng., A 718, 277–286 (2018). https://doi.org/10.1016/j.msea.2018.01.102

    Article  CAS  Google Scholar 

  18. A. D. Kotov, A. V. Mikhaylovskaya, A. A. Borisov, O. A. Yakovtseva, and V. K. Portnoy, “High-strain-rate superplasticity of the Al–Zn–Mg–Cu alloys with Fe and Ni additions,” Phys. Met. Metallogr. 118, 913–921 (2017). https://doi.org/10.1134/S0031918X1709006X

    Article  CAS  Google Scholar 

  19. T. K. Akopyan, N. A. Belov, A. S. Aleshchenko, S. P. Galkin, Y. V. Gamin, M. V. Gorshenkov, V. V. Cheverikin, and P. K. Shurkin, “Formation of the gradient microstructure of a new Al alloy based on the Al–Zn–Mg–Fe–Ni system processed by radial-shear rolling,” Mater. Sci. Eng., A 746, 134–144 (2019). https://doi.org/10.1016/j.msea.2019.01.029

    Article  CAS  Google Scholar 

  20. I. G. Shirinkina and I. G. Brodova, “Annealing-induced structural–phase transformations in an Al–Zn–Mg–Fe–Ni alloy after high pressure torsion,” Phys. Met. Metallogr. 121, 344–351 (2020). https://doi.org/10.1134/S0031918X20040134

    Article  CAS  Google Scholar 

  21. N. A. Belov, V. D. Belov, V. V. Cheverikin, and S. S. Mishurov, “Sparingly alloyed high-strength deformed nickel-aluminum alloys of new generation,” Izv. Vyssh. Uchebn. Zaved., Tsvetn. Metall. 20 (1–2), 49–58 (2011).

    Google Scholar 

  22. I. Brodova, D. Rasposienko, I. Shirinkina, A. Petrova, T. Akopyan, and E. Bobruk, “Effect of severe plastic deformation on structure refinement and mechanical properties of the Al–Zn–Mg–Fe–Ni alloy,” Metals 11, 296 (2021). https://doi.org/10.3390/met11020296

    Article  CAS  Google Scholar 

  23. V. K. Portnoy and I. I. Novikov, “Evaluation of grain boundary sliding contribution to the total strain during superplastic deformation,” Scr. Mater. 40, 39–43 (1998). https://doi.org/10.1016/S1359-6462(98)00394-7

    Article  Google Scholar 

  24. A. V. Mikhaylovskaya, O. A. Yakovtseva, and A. V. Irzhak, “The role of grain boundary sliding and intragranular deformation mechanisms for a steady stage of superplastic flow for Al–Mg-based alloys,” Mater. Sci. Eng., A 833, 142524 (2022). https://doi.org/10.1016/j.msea.2021.142524

    Article  CAS  Google Scholar 

  25. C. Mondal and A. K. Mukhopadhyay, “On the nature of T(Al2Mg3Zn3) and S(Al2CuMg) phases present in as-cast and annealed 7055 aluminum alloy,” Mater. Sci. Eng., A 391, 367–376 (2005). https://doi.org/10.1016/j.msea.2004.09.013

    Article  CAS  Google Scholar 

  26. F.-G. Cong, G. Zhao, F. Jiang, N. Tian, and R. Li, “Effect of homogenization treatment on microstructure and mechanical properties of DC cast 7X50 aluminum alloy,” Trans. Nonferrous Met. Soc. China 25, 1027–1034 (2015). https://doi.org/10.1016/S1003-6326(15)63694-9

    Article  CAS  Google Scholar 

  27. Yo. Zhao, H. Li, Yu. Liu, and Yu. Huang, “The microstructures and mechanical properties of a highly alloyed Al–Zn–Mg–Cu alloy: The role of Cu concentration,” J. Mater. Res. Technol. 18, 122–137 (2022). https://doi.org/10.1016/j.jmrt.2022.02.071

    Article  CAS  Google Scholar 

  28. X. L. Xiao, H. W. Liu, W. L. Chen, and Yi. M. Lin, “Morphology of dispersoids in an annealed Al–Mg alloys,” Mater. Sci. Forum 1035, 72–82 (2021). https://doi.org/10.4028/www.scientific.net/msf.1035.72

  29. S. Sripathi and K. A. Padmanabhan, “Universality of the phenomenology of structural superplasticity,” Mater. Sci. Forum 838839, 84–88 (2016). https://doi.org/10.4028/www.scientific.net/msf.838-839.84

  30. S. Lv, C. Jia, X. He, Z. Wan, X. Li, and X. Qu, “Superplastic deformation and dynamic recrystallization of a novel disc superalloy GH4151,” Materials 12, 3667 (2019). https://doi.org/10.3390/ma12223667

    Article  CAS  Google Scholar 

  31. M. K. Rabinovich and V. G. Trifonov, “Dynamic grain growth during superplastic deformation,” Acta Mater. 44, 2073–2078 (1996). https://doi.org/10.1016/1359-6454(95)00263-4

    Article  CAS  Google Scholar 

  32. P. S. Bate, K. B. Hyde, S. A. Court, and J. F. Humphreys, “Dynamic grain growth in superplastic and non-superplastic aluminium alloys,” Mater. Sci. Forum 447448, 61–66 (2004). https://doi.org/10.4028/www.scientific.net/msf.447-448.61

  33. U. Messerschmidt and M. Bartsch, “Generation of dislocations during plastic deformation,” Mater. Chem. Phys. 81, 518–523 (2003). https://doi.org/10.1016/S0254-0584(03)00064-6

    Article  CAS  Google Scholar 

  34. C. L. Chen and M. J. Tan, “Effect of grain boundary character distribution (GBCD) on the cavitation behaviour during superplastic deformation of Al 7475,” Mater. Sci. Eng., A 338, 243–252 (2002). https://doi.org/10.1016/S0921-5093(02)00083-7

    Article  Google Scholar 

  35. A. V. Mikhaylovskaya, O. A. Yakovtseva, A. G. Mochugovskiy, J. Cifre, and I. S. Golovin, “Influence of minor Zn additions on grain boundary anelasticity, grain boundary sliding, and superplasticity of Al–Mg-based alloys,” J. Alloys Compd. 926, 166785 (2022). https://doi.org/10.1016/j.jallcom.2022.166785

    Article  CAS  Google Scholar 

  36. M. A. Rust and R. I. Todd, “Surface studies of region II superplasticity of AA5083 in shear: Confirmation of diffusion creep, grain neighbour switching and absence of dislocation activity,” Acta Mater. 59, 5159–5170 (2011). https://doi.org/10.1016/j.actamat.2011.04.051

    Article  CAS  Google Scholar 

  37. K. Sotoudeh and P. S. Bate, “Diffusion creep and superplasticity in aluminium alloys,” Acta Mater. 58, 1909–1920 (2010). https://doi.org/10.1016/j.actamat.2009.11.034

    Article  CAS  Google Scholar 

  38. R. I. Todd, “Critical review of mechanism of superplastic deformation in fine grained metallic materials,” Mater. Sci. Technol. 16, 1287–1294 (2000). https://doi.org/10.1179/026708300101507118

    Article  CAS  Google Scholar 

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ACKNOWLEDGMENTS

TEM was performed at the Center for Collective Use of MISIS “Materials Science and Metallurgy”.

Funding

This work was supported by the Russian Federation President Grant for supporting leading scientific schools NSh-1752.2022.4.

The Center for Collective Use of MISIS “Materials Science and Metallurgy” was equipped using the project of the State task of the Russian Federation for the purchase of equipment no. 075-15-2021-696.

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Correspondence to O. A. Yakovtseva.

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Translated by T. Gapontseva

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Yakovtseva, O.A., Postnikova, M.N., Irzhak, A.V. et al. Effect of Ni on the Contributions of Superplastic Deformation Mechanisms in an Al–Zn–Mg–Cr Alloy. Phys. Metals Metallogr. 124, 944–954 (2023). https://doi.org/10.1134/S0031918X23601464

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