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Investigation of the Magnetocaloric Properties in Cu1.5[Fe(CN)6]⋅H2O and Mn1.5[Fe(CN)6]⋅zH2O

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Abstract

In this work, it is used a phenomenological model to predict the thermomagnetic properties for Cu1.5[Fe(CN)6]⋅zH2O and Mn1.5[Fe(CN)6]⋅zH2O through making modeling of experimental isofield thermo-magnetization curves. Consequently, the magnetocaloric effect (MCE) of Cu1.5[Fe(CN)6]⋅zH2O and Mn1.5[Fe(CN)6]⋅zH2O, in the vicinity of ferromagnetic phase transition, is simulated, calculating MCE parameters. The comparison between MCE of Cu1.5[Fe(CN)6]⋅zH2O and Mn1.5[Fe(CN)6]⋅zH2O samples, and other some reported magnetic materials has been done, showing that MCE parameters of Cu1.5[Fe(CN)6]⋅zH2O and Mn1.5[Fe(CN)6]⋅zH2O samples are larger than some MCE parameters of these reported magnetic materials. The behavior of MCE in Cu1.5[Fe(CN)6]⋅zH2O and Mn1.5[Fe(CN)6]⋅zH2O recommends that they can fruitfully be utilized as cryogenic magnetic refrigerants between 5 and 25 K especially in radiation detectors for outer space research.

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Hamad, M.A., Alamri, H.R. Investigation of the Magnetocaloric Properties in Cu1.5[Fe(CN)6]⋅H2O and Mn1.5[Fe(CN)6]⋅zH2O. Phys. Metals Metallogr. 122, 1458–1462 (2021). https://doi.org/10.1134/S0031918X21140222

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