Abstract
Diffusion filtering metallic palladium–yttrium membranes are subjected to hydrogenation from a gas phase and are studied by X-ray diffraction using synchrotron radiation. Boundaries of the formation of hydrogen-enriched phases are improved for a range of alloying component content, which is critical for their formation. The effect of the initial state of the alloy on conditions of hydride phase formation in the system is demonstrated. The content of hydrogen occluded in the membrane structure and hydrogen-induced lattice dilatations are determined. The parameters of the alloy substructure are calculated.
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ACKNOWLEDGMENTS
The X-ray investigation of the structure was carried out using the unique research installation Kurchatov synchrotron radiation source in the National Research Center Kurchatov Institute.
Funding
The study was partly supported by the Ministry of Science and Higher Education of the Russian Federation, Federal Target Program Research and Development in Priority Directions of Scientific and Technological Complex of Russia in 2014–2020 (agreement no. 14.619.21.0007, unique identification no. RFMEFI61917X0007).
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Translated by N. Kolchugina
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Akimova, O.V., Veligzhanin, A.A., Svetogorov, R.D. et al. Kinetics of Hydrogen Absorption from a Gas Phase by Diffusion Filtering Pd–Y Membranes. Phys. Metals Metallogr. 121, 157–163 (2020). https://doi.org/10.1134/S0031918X20020027
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DOI: https://doi.org/10.1134/S0031918X20020027