Abstract
The nanostructure of the ODS Eurofer steel (9% CrWVTa + 0.5% Y2O3) has been studied after irradiation by iron ions to a damaging dose of 32 dpa. This steel in the initial state is characterized by the presence of a significant amount (∼1024 m−3) of nanosized (2–4 nm) clusters containing atoms of V, Y, O, and N. An analysis of the distribution of various chemical elements in the tested volumes has revealed variations in the composition of the matrix and of the nanosized clusters during irradiation. The data obtained were compared with the results for the ODS Eurofer steel subjected to reactor irradiation to a dose of 32 dpa.
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R. Lindau, A. Moslang, M. Schirra, P. Schlossmacher, and M. Klimenkov, “Mechanical and microstructural properties of a hipped RAFM ODS-steel,” J. Nucl. Mater. 307–311, 769–772 (2002).
R. L. Klueh, P. J. Maziasz, I. S. Kim, L. Heatherly, D. T. Hoelzer, and N. Hashimoto, “Tensile and creep properties of an oxide dispersion-strengthened ferritic steel,” J. Nucl. Mater. 307–311, 773–777 (2002).
R. Lindau, A. Moslang, M. Rieth, M. Klimiankou, E. Materna-Morris, A. Alamo, A. A. F. Tavassoli, C. Cayron, A. M. Lancha, P. Fernandez, N. Baluc, R. Schaeublin, E. Diegele, G. Filacchioni, J. W. Rensman, B. V. D. Schaaf, E. Lucon, and W. Dietz, “Present development status of EUROFER and ODS-EUROFER for application in blanket concepts,” Fusion Eng. Des. 75–79, 989–996 (2005).
L. Debarberis, B. Acosta, A. Zeman, F. Sevini, A. Ballesteros, A. Kryukov, F. Gillemot, and M. Brumovsky, “Analysis of WWER-440 and PWR RPV welds surveillance data to compare irradiation damage evolution,” J. Nucl. Mater. 350, 173–181 (2006).
S. V. Rogozhkin, A. A. Nikitin, A. A. Aleev, A. G. Zaluzhnyi, A. A. Chernobaeva, D. Yu. Erak, Ya. I. Shtrombakh, and O. O. Zabusov, “Study of the thin structure of welded seam with high content of phosphorus of WWER-440 reactor vessel after annealing and repeated irradiation,” Yadern. Fiz. Inzhinir. 4, 73–82 (2013).
A. Kryukov, L. Debarberis, A. Ballesteros, V. Krsjak, R. Burcl, S. V. Rogozhkin, A. A. Nikitin, A. A. Aleev, A. G. Zaluzhnyi, V. I. Grafutin, O. Ilyukhina, Yu. V. Funtikov, and A. Zeman, “Integrated analysis of WWER-440 RPV weld re-embrittlement after annealing,” J. Nucl. Mater. 429, 190–200 (2012).
R. Schaeublin, T. Leguey, P. Spatig, N. Baluc, and M. Victoria, “Microstructure and mechanical properties of two ODS ferritic/martensitic steels,” J. Nucl. Mater. 307–311, 778–782 (2002).
C. Petersen, V. Shamardin, A. Fedoseev, G. Shimansky, V. Efimov, and J. J. Rensman, “The ARBOR irradiation project,” J. Nucl. Mater. 307–311, 1655–1659 (2002).
C. Petersen, A. Povstyanko, V. Prokhorov, A. Fedoseev, O. Makarov, and B. Dafferner, “Impact property degradation of ferritic/martensitic steels after the fast reactor irradiation ‘ARBOR 1’,” J. Nucl. Mater. 367–370, 544–549 (2007).
J. Henry, X. Averty, and A. Alamo, “Tensile and impact properties of 9Cr tempered martensitic steels and ODS-FeCr alloys irradiated in a fast reactor at 325°C up to 78 dpa,” J. Nucl. Mater. 417, 99–103 (2011).
M. Klimenkov, R. Lindau, and A. Moslang, “HRTEM study of yttrium oxide particles in ODS steels for fusion reactor application,” J. Cryst. Growth 249, 381–387 (2003).
A. A. Aleev, N. A. Iskandarov, M. Klimenkov, R. Lindau, A. Moslang, A. A. Nikitin, S. V. Rogozhkin, P. Vladimirov, and A. G. Zaluzhnyi, “Investigation of oxide particles in unirradiated ODS Eurofer by tomographic atom probe,” J. Nucl. Mater. 409, 65–71 (2011).
S. V. Rogozhkin, T. V. Kulevoi, N. A. Iskandarov, N. N. Orlov, B. B. Chalykh, A. A. Aleev, N. Yu. Grachev, R. P. Kuibida, A. A. Nikitin, A. D. Fertman, and V. B. Shishmarev, “Simulation experiment on the study of the radiation resistance of a promising ferritic-martensitic steel strengthened by disperse inclusions,” At. Energy 114, 14–20 (2013).
S. V. Rogozhkin, V. S. Ageev, A. A. Aleev, A. G. Zaluzhnyi, M. V. Leont’eva-Smirnova, and A. A. Nikitin, “Tomographic atom probe analysis of temperature resistant 12% chromium ferritic-martensitic EK-181 steel,” Phys. Met. Metallogr. 108, 579–585 (2009).
S. V. Rogozhkin, N. A. Iskandarov, A. A. Aleev, A.G. Zaluzhnyi, A. A. Nikitin, M. V. Leont’evaSmirnova, and E. M. Mozhanov, “Study of the nanoscale state of ferritic-martensitic steel Rusfer EK-181 after various heat treatments, Inorg. Mater.: Appl. Res. 3, 129–134 (2012).
S. V. Rogozhkin, A. A. Aleev, A. G. Zaluzhnyi, A. A. Nikitin, N. A. Iskandarov, P. Vladimirov, R. Lindau, and A. Moslang, “Atom probe characterization of nano-scaled features in irradiated ODS Eurofer steel,” J. Nuclear Mater. 409, 94–99 (2011).
S. V. Rogozhkin, A. A. Aleev, A. G. Zaluzhnyi, R. P. Kuibida, T. V. Kulevoi, A. A. Nikitin, N. N. Orlov, B. B. Chalykh, and V. B. Shishmarev, “Atom probe tomography of nanoscaled features of oxide-dispersion-strengthened (ODS) Eurofer steel under the action of heavy ion radiation,” Yadern. Fiz. Inzh. 3, 373–379 (2012).
S. V. Rogozhkin, A. A. Aleev, A. G. Zaluzhnyi, R. P. Kuibida, T. V. Kulevoi, A. A. Nikitin, N. N. Orlov, B. B. Chalykh, and V. B. Shishmarev, “Effect of irradiation by heavy ions on the nanostructure of perspective materials for nuclear power plants,” Phys. Met. Metallogr. 113, 200–211 (2012).
T. Kulevoy, R. Kuibeda, G. Kropachev, A. Kozlov, B. Chalyh, A. Aleev, A. Fertman, A. Nikitin, and S. Rogozhkin, “ITEP MEVVA ion beam for reactor material investigation,” Rev. Sci. Instrum. 81, 02B906 (2010).
G. N. Kropachev, V. B. Shishmarev, R. P. Kuibida, B.B. Chalykh, S. V. Plotnikov, S. V. Rogozhkin, A. A. Aleev, A. A. Nikitin, N. N. Orlov, D. N. Seleznev, and T. V. Kulevoi, “Preparation of imitation experiment on iron ion beam for study of the radiation stability of reactor steels,” Yadern. Fiz. Inzhin. 2, 538–542 (2011).
M. K. Miller, Atom Probe Tomography: Analysis at the Atomic Level (Kluwer Academic, New York, 2000).
A. Cerezo and L. Davin, “Aspects of the observation of clusters in the 3-dimensional atom probe,” Surf. Interface Anal. 39, 184–188 (2007).
J. M. Hyde, E. A. Marquis, K. B. Wilford, and T. J. Williams, “A sensitivity analysis of the maximum separation method for the characterisation of solute clusters,” Ultramicroscopy 111, 440–447 (2011).
S. V. Rogozhkin, A. A. Aleev, A. G. Zaluzhnyi, N. A. Iskandarov, A. A. Nikitin, P. Vladimirov, R. Lindau, and A. Moslang, “Atom probe tomography of nanoscaled features of oxide-dispersion-strengthened (ODS) Eurofer steel in the initial state and after neutron irradiation,” Phys. Met. Metallogr. 113, 98–105 (2012).
M. Klimenkov, R. Lindau, and A. Moslang, “New insights into the structure of ODS particles in the ODS-Eurofer alloy,” J. Nucl. Mater. 386–388, 553–556 (2009).
M. Klimiankou, R. Lindau, and A. Moslang, “Direct correlation between morphology of (Fe,Cr)23C6 precipitates and impact behavior of ODS steels,” J. Nucl. Mater. 367–370, 173–178 (2007).
V. Castro, T. Leguey, A. Mucoz, M. A. Monge, P. Fernández, A. M. Lancha, and R. Pareja, “Mechanical and microstructural behavior of Y2O3 ODS Eurofer 97,” J. Nucl. Mater. 367–370, 196–201 (2007).
S. Rogozkin, A. Chernobaeva, A. Aleev, A. Nikitin, A. Zaluzhnyi, D. Erak, Ya. Shtrombakh, O. Zabusov, L. Debarberis, and A. Zeman, “The effect of post-irradiation annealing on VVER-440 RPV materials mechanical properties and nanostructure under reirradiation,” Proc. PVP2009, 2009 ASME Pressure Vessels and Piping Division Conf., Prague, Czech Republic, 2009 PVP2009-78128.
N. V. Luzginova, J. Rensman, P. Pierick, and J. B. J. Hegeman, “Irradiation response of ODS Eurofer 97 steel,” J. Nucl. Mater. 428, 192–196 (2012).
D. A. McClintock, M. A. Sokolov, D. T. Hoelzer, and R. K. Nanstad, “Mechanical properties of irradiated ODS-Eurofer and nanocluster strengthened 14YWT,” J. Nucl. Mater. 392, 353–359 (2009).
E. Lucon, A. Leenaers, and W. Vandermeulen, “Mechanical response of oxide dispersion strengthened (ODS) Eurofer-97 after neutron irradiation at 300°C,” Fusion Eng. Des. 82, 2438–2443 (2007).
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Original Russian Text © S.V. Rogozhkin, N.N. Orlov, A.A. Aleev, A.G. Zaluzhnyi, M.A. Kozodaev, R.P. Kuibeda, T.V. Kulevoy, A.A. Nikitin, B.B. Chalykh, R. Lindau, A. Möslang, P. Vladimirov, 2015, published in Fizika Metallov i Metallovedenie, 2015, Vol. 116, No. 1, pp. 76–82.
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Rogozhkin, S.V., Orlov, N.N., Aleev, A.A. et al. Nanostructure evolution in ODS Eurofer steel under irradiation up to 32 dpa. Phys. Metals Metallogr. 116, 72–78 (2015). https://doi.org/10.1134/S0031918X15010093
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DOI: https://doi.org/10.1134/S0031918X15010093