Abstract
The metastable austenitic iron alloy with 31.3 wt % Ni (N31) has been used to show the possibility of the formation of a nickel-concentration inhomogeneity in a fine-grained austenite due to an α → γ trans-formation under the condition of a preliminary formation of a nickel-enriched intermediate nanocrystalline γ phase. The thermal expansion coefficients (TECs) in the range of −100 to +300°C have been estimated in concentrationally inhomogeneous steel N31 after various heat treatments. The conditions necessary to ensure the possibility of controlling the TEC in wide limits have been found.
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References
Y. Estrin and A. Vinogradov, “Extreme grain refinement by severe plastic deformation: A wealth of challenging science,” Acta Mater. 61, 782–817 (2013).
R. A. Andrievskii and A. M. Glezer, “Strength of nanostructures,” Phys.-Usp. 52, 315–334 (2009)
N. I. Noskova, V. V. Shulika, A. G. Lavrent’ev, A. P. Potapov, and G. S. Korzunin, “Structure and magnetic properties of iron-and cobalt-based amorphous alloys versus nanocrystallization conditions,” Tech. Phys. 50, 1311–1315 (2005).
A. Inoue, “Bulk high strength amorphous alloys with low critical rates,” Mater. Trans. JIM 36, 866–875 (1995).
V. V. Sagaradze and I. G. Kabanova, “Formation of nanocrystalline structure during direct and reverse martensitic transformations,” Mater. Sci. Eng., A 273–275, 457–461 (1999).
V. V. Sagaradze, V. A. Shabashov, V. E. Danilchenko, and Ph. L’Heritier, “The structure and properties of Fe-Ni alloys with a nanocrystalline austenite formed under different conditions of Γ → α → Γ transformations,” Mater. Sci. Eng., A 337, 146–159 (2002).
K. A. Malyshev, V. V. Sagaradze, I. P. Sorokin, N. D. Zemtsova, V. A. Teplov, and A. I. Uvarov, Phase-Transformation Hardening of Iron-Nickel-Based Austenite Alloys (Nauka, Moscow, 1982) [in Russian].
V. V. Sagaradze and A. I. Uvarov, Strength and Properties of Austenitic Steels (Ural. Otd. Ross. Akad. Nauk, Ekaterinburg, 2013) [in Russian].
V. V. Sagaradze, “The structure and properties of ironbased nanocrystalline alloys produced using cyclic martensitic transformations,” in Severe Plastic Deformations: Toward Bulk Production of Nanostructured Materials, Ed. by A. Burhanettin (Nova Science, 2050), pp.153–167.
V. V. Sagaradze, V. E. Danil’chenko, and Ph. L’Heritier, “Transformation-induced hardening and the formation of Fe-Ni nanocrystalline austenite upon Γ→α→ Γ transformations,” Phys. Met. Metallogr. 92, 371–385 (2001).
M. Hansen and K. Anderko, The Constitution of Binary Alloys (McGraw-Hill, New York, 1958; Metallurgiya, Moscow, 1962).
I. V. Svechkarev, “Balance with autocompensation for magnetic susceptibility measurements,” Prib. Tekh. Eksp., No. 4, 142–143 (1963).
A. Hirano, M. Cohen, and B. Averbach, “Diffusion of nickel into iron,” Acta Metall. 9, 440–445 (1961).
V. V. Sagaradze, K. A. Malyshev, V. M. Schastlivtsev, Yu. A. Vaseva, and L. M. Proleeva, “Effect of heating rate on the reverse α → Γ transformation in iron with 31.5% nickel alloy,” Fiz. Met. Metalloved. 39, 1239–1250 (1975).
P. J. Shewmon, “Diffusion,” in Physical Metallurgy, Ed. by. R. W. Cahn (North-Holland, Amsterdam, 1965; Mir, Moscow, 1968).
I. G. Kabanova, V. V. Sagaradze, and N. V. Kataeva, “Detection of the ɛ phase and the Headley-Brooks orientation relationships upon α → Γ transformation in the Fe-32% Ni alloy,” Phys. Met. Metallogr. 112, 381–388 (2011).
I. G. Kabanova, V. V. Sagaradze, and N. V. Kataeva, “Formation of an L10 superstructure in austenite upon the α → Γ transformation in the invar alloy Fe-32% Ni,” Phys. Met. Metallogr. 112, 267–276 (2011).
V. V. Sagaradze, I. G. Kabanova, N. V. Kataeva, and M. F. Klyukina, “Structural mechanism of reverse α→Γ transformation and new functional properties of Fe-Ni austenitic alloys,” Mater. Sci. Forum 738–739, 200–205 (2013).
V. A. Shabashov, V. V. Sagaradze, E. E. Yurchikov, and A. V. Savel’eva, “Mössbauer and electron-microscopic study of α → Γ transformation and stabilization of iron-nickel austenite,” Fiz. Met. Metalloved. 44, 1060–1070 (1977).
R. Bozorth, Ferromagnetism (Toronto, 1951; Inostrannaya Literatura, Moscow, 1956).
W. C. Leslie and R. Z. Mieler, “The stabilization of austenite by closely-spaced boundaries,” Trans. Metall. Soc. AIME. 57, 972–979 (1964).
E. P. Blinova, A. M. Glezer, N. B. D’yakonova, and V. V. Zhorin, “Size effect upon martensitic transformations in iron-nickel alloys quenched from the melt,” Izv. Akad. Nauk, Ser. Fiz. 65, 1444–1449 (2001).
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Original Russian Text © V.V. Sagaradze, V.A. Zavalishin, N.V. Kataeva, I.G. Kabanova, I.I. Kositsina, M.F. Klyukina, A.I. Valiullin, V.A. Kazantsev, 2014, published in Fizika Metallov i Metallovedenie, 2014, Vol. 115, No. 5, pp. 517–531.
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Sagaradze, V.V., Zavalishin, V.A., Kataeva, N.V. et al. Using an intermediate nanocrystalline γ phase for producing austenitic steels with a controllable thermal expansion coefficient. Phys. Metals Metallogr. 115, 486–499 (2014). https://doi.org/10.1134/S0031918X14050081
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DOI: https://doi.org/10.1134/S0031918X14050081