Abstract
Mössbauer spectroscopy at 119Sn and 57Fe nuclei was used to study thermally induced processes of phase formation in two-layered systems Sn(4 μm)-Fe(10 μm) obtained by ion-plasma deposition. The layered systems were subjected to sequential isothermal annealings at 550°C and 700°C to show the formation of intermetallic compounds FeSn and Fe3Sn2 and of an α-Fe(Sn) solid solution. It has also been shown that the nature of the phase transformations is determined by a change in the local concentration of tin in the sample in the process of diffusion of the atomic components. Thermally stable spatially inhomogeneous systems FeSn/α-Fe(Sn) and Fe3Sn2/α-Fe(Sn) have been obtained.
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References
I. I. Novikov, Theory of Metal Heat Treatment (Metallurgiya, Moscow, 1986) [in Russian].
P. T. Kolomytsev, High-Temperature Protective Coatings for Nickel Alloys (Metallurgiya, Moscow, 1991) [in Russian].
Phase Diagrams of Binary Metal Systems: A Handbook, in three volumes, Ed. by N. P. Lyakishev (Mashinostroenie, Moscow, 1997) [in Russian].
V. S. Rusakov, Mössbauer Spectroscopy of Locally Inhomogeneous Systems (OPNI Inst. Yadern. Fiz., Nat. Yadern. Tsentr Resp. Kazakhstan, Almaty, 2000) [in Russian].
C. Djega-Mariadassou, P. Lecocq, G. Trumpy, et al., “Mössbauer Study on FeSn and Fe3Sn,” Nuovo Cimento B 46(1), 35–45 (1966).
S. K. Kulshreshtha and P. Raj, “Anisotropic Hyperfine Fields in FeSn by Mössbauer Spectroscopy,” J. Phys. F: Met. Phys. 11, 281–291 (1981).
S. Ichiba, H. Sakai, and H. Negita, “The Mössbauer Effect in Fe3Sn2,” Bull. Chem. Soc. Jpn. 41(11), 2791–2792 (1968).
G. Le Caer, B. Malaman, L. Haggstrom, and T. Ericsson, “Magnetic Properties of Fe3Sn2. III. A 119Sn Mössbauer Study,” J. Phys. F: Met. Phys. 9(9), 1905–1919 (1979).
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Original Russian Text © A.K. Zhubaev, V.S. Rusakov, K.K. Kadyrzhanov, 2010, published in Fizika Metallov i Metallovedenie, 2010, Vol. 109, No. 5, pp. 497–504.
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Zhubaev, A.K., Rusakov, V.S. & Kadyrzhanov, K.K. Study of thermal stabilization of an intermetallic compound-α-Fe(Sn) solid solution layered system. Phys. Metals Metallogr. 109, 461–468 (2010). https://doi.org/10.1134/S0031918X10050066
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DOI: https://doi.org/10.1134/S0031918X10050066