Abstract
Precipitation hardening alloys of the Ti-Ta-C and Ti-Zr-C systems produced by self-propagating high-temperature synthesis (SHS) have been studied. Optimum compositions of the alloys and heat-treatment conditions, under which the decomposition of supersaturated solid solution accompanied by the precipitation of fine particles both inside carbide grains and at their boundaries occurs, have been determined. The precipitation hardening ceramic materials exhibit high hardness (∼15–23 GPa) and heat resistance (the mass increase of the Ti-9.4% Ta-10.5% C alloy is less than 8 g/m2 during a 50-h exposure in air at 800°C) and can be recommended for the application as materials for deposited multifunctional coatings, high-temperature contacts, evaporation crucibles, and abrasion-resistive tools.
Similar content being viewed by others
References
E. A. Levashov, D. V. Shtansky, A. L. Lobov, and I. P. Borovinskaya, “Structure and Properties of a New Disperse-Hardening Alloy Based on Titanium Carbide Obtained by the SHS Method,” Int. J. SHS 2(2), 165 (1994).
E. A. Levashov, D. V. Shtanskii, A. L. Lobov, et al., “Structure and Properties of New TiC-Based Precipitation-Hardening Alloy Manufactured by Self-Propagating High-Temperature Synthesis,” Fiz. Met. Metalloved. 77(2), 118–124 (1994) [Phys. Met. Metallogr. 77 (2), 179–184 (1994)].
J. C. LaSalvia, D. K. Kim, and M. A. Meyers, “Effect of Mo on Microstructure and Mechanical Properties of TiC-Ni Based Cermets Produced by Combustion Synthesis-Impact Forging Technique,” Mater. Sci. Eng, A 206(1), 71–80 (1996).
E. A. Levashov, B. V. Vyushkov, K. N. Egorychev, and I. P. Borovinskaya, “Technological Aspects of Manufacturing New Synthetic Titanium and Molybdenum Carbide-Based Tool Materials,” Int. J. SHS 5(3), 293 (1996).
E. A. Levashov, D. V. Shtanskii, B. V. V’yushkov, and E. V. Shtanskaya, “Formation of the Structure of Titanium-Carbide-Based Alloys TiC-Mo-Ni and TiC-Mo Systems during Self-Propagating High-Temperature Compacting,” Fiz. Met. Metalloved. 78(4) 147–153 (1994) [Phys. Met. Metallogr. 78 (4) 454–459 (1994)].
E. A. Levashov and V. V. Kurbatkina, “Regularities of Composite Materials with Micrograded Grain Structure Formation,” in Functionally Graded Materials VIII(FGM 2004), Ed. by Omer Van der Biest, M. Gasik, and J. Vleugels (Leuven, Belgium, 2004); Mater. Sci. Forum, 492–493, 615–620 (2004).
V. V. Kurbatkina, E. A. Levashov, and D. A. Podgornyi, “Composite Materials with a Micrograded Structure of Grains,” Tsvetn. Metall., No. 2, 61–64 (2006).
A. I. Gusev, Nonstoichiometry, Disorder, Short-Range and. Long-Range Order in Solids (Moscow: Izd-vo Fizmatlit,. 2007) Nonstoichiometry, Disorder, Short-Range and Long-Range Order in Solids (Nauka-Fizmatlit, Moscow, 2007) [in Russian].
E. K. Storms, The Refractory Carbides (Academic, New York, 1967; Atomizdat, Moscow, 1970).
S. S. Kiparisov, Yu. V. Levinskii, and V. M. Petrov, Titanium Carbide: Production, Properties, and Applications (Metallurgiya, Moscow, 1989) [in Russian].
E. A. Levashov, A. S. Rogachev, V. I. Yukhvid, and I. P. Borovinskaya, Physico-Chemical and Technologic Basis of Self-Propagating High-Temperature Synthesis (Binom, Moscow, 1999) [in Russian].
K. A. Babayan, V. P. Kobyakov, L. B. Mashkinov, and I. D. Chashechkin, “Heat-Release Measurement in “Gasless” Combustion of a Titanium-Carbon Mixture in a Nonhermetic Shell,” Combustion, Explosion, and Shock Wave 32(1), 41–44 (1996).
S. S. Gorelik, Yu. A. Skakov, and L. N. Rastorguev, X-ray and Electron-Optical Analysis (MISiS, Moscow, 1999) [in Russian].
GOST 9450-67 or E-384-89, Method of Measuring Microhardness of Materials (ASTM standard).
V. I. Tumanov, A. I. Brokhin, E. I. Timoshenko, et al., “On the Method of Measurement of Solid Alloy Hardness,” in Solid Alloys, Scientific Works of VNIITS (Metallurgiya, Moscow, 1973), No. 12, pp. 98–103.
G. V. Samsonov, G. Sh. Upadkhaya, and V. S. Neshpor, Physical Metallurgy of Carbides (Naukova Dumka, Kiev, 1974) [in Russian].
W. B. Pearson, Handbook of Lattice Spacings and Structures of Metal Alloys (Pergamon, New York, 1967).
E. A. Levashov, V. V. Kurbatkina, A. S. Rogachev, et al., “Peculiarities of Burning and Structure Formation in Ti-Ta-C System,” Izv.Vyssh. Uchebn. Zaved., Poroshk. Metall. Funkt. Pokr., No. 2, 25–35 (2008).
E. A. Levashov, A. S. Rogachev, Yu. K. Epishko, and N. A. Kochetov, “Self-Propagating High-Temperature Synthesis of Target Cathodes in Ti-Ta-C-Ca3(PO4)2 for Ion-Plasma Deposition of Multifunctional Biocompatible Nanostructural Coatings,” Izv.Vyssh. Uchebn. Zaved., Poroshk. Metall. Funk. Pokr., No. 1, 14–26 (2007).
O. Kubaschewski and B. E. Hopkins, Oxidation of Metals and Alloys (Butterworths, London, 1962; Mir, Moscow, 1969).
R. F. Voitovich and E. A. Pugach, Oxidation of Refractory Compounds: A Handbook (Metallurgiya, Moscow, 1978) [in Russian].
G. V. Samsonov and A. L. Borisova, et al., Physicochemical Properties of Oxides: A Handbook (Metallurgiya, Moscow, 1978) [in Russian].
S. A. Aivazyan, I. S. Enyukov, and L. D. Meshalkin, The Applied Statistics. Dependency Analysis: A Handbook (Finansy i Statistika, Moscow, 1985) [in Russian].
Author information
Authors and Affiliations
Additional information
Original Russian Text © E.A. Levashov, V.V. Kurbatkina, A.A. Zaitsev, S.I. Rupasov, E.I. Patsera, A.A. Chernyshev, Ya.V. Zubavichus, A.A. Veligzhanin, 2010, published in Fizika Metallov i Metallovedenie, 2010, Vol. 109, No. 1, pp. 102–112.
Rights and permissions
About this article
Cite this article
Levashov, E.A., Kurbatkina, V.V., Zaitsev, A.A. et al. Structure and properties of precipitation-hardening ceramic Ti-Zr-C and Ti-Ta-C materials. Phys. Metals Metallogr. 109, 95–105 (2010). https://doi.org/10.1134/S0031918X10010102
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0031918X10010102