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Kinetics of dissolution of phases upon deformation of nanostructured metals and alloys

  • Theory of Metals
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Abstract

The kinetic features of dissolution of foreign inclusions in the bulk of nanostructured metals upon plastic deformation have been discussed. It has been shown that the rate of dissolution of inclusions substantially depends on the character of structural transformations in the subsystem of intercrystallite boundaries of nanomaterials. Equations that determine the kinetics of dissolution of chemical compounds of metals depending on the rate of structural transformations in intercrystallite boundaries upon deformation have been obtained. The behavior of the kinetic curves of dissolution has been described qualitatively. Numerical estimates of the time of dissolution of inclusions Fe3C and Fe2B in steels are given which are in satisfactory agreement with experimental data on the mechanical alloying of iron with nonmetals in ball planetary mills.

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References

  1. L. S. Vasil’ev and S. F. Lomayeva, “On the Analysis of Mechanism of Super Saturation of Metal Powders with Interstitial Impurities during Mechanoactivation,” J. Mater. Sci. 3, 5411–5415 (2004).

    Article  Google Scholar 

  2. L. S. Vasil’ev, I. L. Lomaev, and E. P. Elsukov, “On the Analysis of the Mechanisms of the Strain-Induced Dissolution of Phases in Metals,” Fiz. Met. Metalloved. 102(2), 201–213 (2006) [Phys. Met. Metallogr. 102 (2), 186–197 (2006)].

    CAS  Google Scholar 

  3. L. S. Vasil’ev and I. L. Lomaev, “On Possible Mechanisms of Nanostructure Evolution upon Severe Plastic Deformation of Metals and Alloys,” Fiz. Met. Metalloved. 101(4), 417–424 (2006) [Phys. Met. Metallogr. 101 (4), 386–393 (2006)].

    CAS  Google Scholar 

  4. V. V. Sagaradze, “Strain-Induced Phase Transformations and Their Influence on the Structure and Properties of Alloys,” in New Perspective Materials and New Technologies (Ural. Otd. Ross. Akad. Nauk, Ekaterinburg, 2001), pp. 158–195 [in Russian].

    Google Scholar 

  5. B. Ya. Lyubov, Kinetic Theory of Phase Transformations (Metallurgiya, Moscow, 1969; Amerind, New Dehli, 1978; National Bureau of Standards, Gaithersburg, MD, 1978).

    Google Scholar 

  6. L. D. Landau and E. M. Lifshitz, Statistical Physics, Part 1 (Pergamon, Oxford, 1980; Fizmatlit, Moscow, 2005).

    Google Scholar 

  7. V. M. Finkel’, V. A. Fedorov, and A. P. Korolev, Fracture of Crystals upon Mechanical Twinning (Izd. Rostov. Univ., Rostov-on-Don, 1990) [in Russian].

    Google Scholar 

  8. E. P. Elsukov, I. V. Povstugar, A. L. Ul’yanov, et al., “Deformation-Induced Dissolution of the Fe2B Boride in Nanocrystalline α-Fe,” Fiz. Met. Metalloved. 101(2), 193–199 (2006) [Phys. Met. Metallogr. 101 (2), 174–181 (2006)].

    CAS  Google Scholar 

  9. V. M. Kosevich, V. M. Ievlev, L. S. Palatnik, et al., Structure of Intercrystallite and Interphase Interfaces (Metallurgiya, Moscow, 1980) [in Russian].

    Google Scholar 

  10. J. Hirth and J. Lothe, Theory of Dislocation (McGraw-Hill, New York, 1968; Atomizdat, Moscow, 1972).

    Google Scholar 

  11. V. L. Gapontsev and V. V. Kondrat’ev, “Diffusion Phase Transformations in Nanocrystalline Alloys under Severe Plastic Deformation,” Dokl. Akad. Nauk 385(5), 608–611 (2002) [Dokl. Phys. 47 (8), 576–579 (2002)].

    MATH  Google Scholar 

  12. B. B. Khina, G. F. Lovshenko, V. M. Konstantinov, and B. Formanek, “Mathematical Model of Solid-State Diffusion upon Periodical Plastic Deformation,” Metallofiz. Noveishie Tekhnol. 27(5), 609–623 (2005).

    CAS  Google Scholar 

  13. Ya. E. Geguzin and M. A. Krivoglaz, Migration of Macroscopic Inclusions in Solids (Metallurgiya, Moscow, 1971; Consultants Bureau, New York, 1973).

    Google Scholar 

  14. L. S. Vasil’ev, “Possible Mechanism of Low-Temperature Crystallization of Amorphous Structures during Deformation,” in Proc. First Int. Symp. on Melting and Crystallization of Metals and Alloys-MSMO-2007 (IPO PI YuFU, Rostov-on-Don, 2007), pp. 38–42.

    Google Scholar 

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Authors and Affiliations

  1. Physicotechnical Institute, Ural Division, Russian Academy of Sciences, ul. Kirova 132, Izhevsk, 426000, Russia

    L. S. Vasil’ev, I. L. Lomaev & E. P. Elsukov

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  1. L. S. Vasil’ev
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  2. I. L. Lomaev
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  3. E. P. Elsukov
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Original Russian Text © L.S. Vasil’ev, I.L. Lomaev, E.P. Elsukov, 2009, published in Fizika Metallov i Metallovedenie, 2009, Vol. 107, No. 2, pp. 152–162.

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Vasil’ev, L.S., Lomaev, I.L. & Elsukov, E.P. Kinetics of dissolution of phases upon deformation of nanostructured metals and alloys. Phys. Metals Metallogr. 107, 141–150 (2009). https://doi.org/10.1134/S0031918X09020057

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  • DOI: https://doi.org/10.1134/S0031918X09020057

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