Abstract
The hydrogen storage capacity of titanium aluminides Ti(Al,Nb) (β0) and Ti3 (Al,Nb) (α2) subjected to mechanoactivation has been investigated. It has been found that the mechanoactivation in a hydrogen atmosphere makes it possible to obtain hydrides of titanium aluminides with a hydrogen concentration of up to 1.8 wt % at room temperature without enhanced requirements for purity and pressure of the supplied hydrogen. The release of hydrogen from such samples in a vacuum begins at a temperature of about 175°C.
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References
Hydrogen in Metals, Ed by G. Alefeld, J. Volkl (Springer, New York, 1978, Mir, Moscow, 1981), Vols. 1–2.
K. M. Semenenko, V. V. Burnasheva, and V. N. Verbetskii, “Interaction of Hydrogen with Intermetallic Compounds,” Dokl. Akad. Nauk SSSR 270(6), 1404–1413 (1983).
K. N. Semenenko, V. A. Yartys’, and V. V. Burnasheva, “Crystal Lattice Deformation and Relation of Intermetallic Compounds to Hydrogen,” Dokl. Akad. Nauk SSSR 245(5), 1127–1135 (1979).
V. V. Burnasheva and K. N. Semenenko, “Interaction of Hydrogen with Intermetallic Compounds,” Zh. Obshch. Khim. 58(9), 1931 (1986).
D. G. Westlake, “Site Occupancies and Stoichiometries in Hydrides of Intermetallic Compounds: Geometric Considerations,” J. Less-Common Met. 90, 251–273 (1983).
Yu. R. Kolobov, R. Z. Valiev, I. P. Grabovitskaya, et al., Grain-Boundary Diffusion and Properties of Nanostructured Materials (Nauka, Novosibirsk, 2001) [in Russian].
I. G. Konstanchuk, E. Yu. Ivanov, and V. V. Boldyrev, “Interaction of Hydrogen with Alloys and Intermetallic Compounds Obtained by Mechanochemical Methods,” Usp. Khim. 67(1), 75–86 (1998) [Russ. Chem. Rev. 67 (1), 69–79 (1998)].
E-MRS Spring Meeting 2003, Strasbourg, France, June 10–13, 2003, Symposium C, “Nanoscale Materials for Energy Storage”. http://www.e-mrs.org/.
S. Orimo and H. Fujii, “Materials Science of Mg-Ni-Based New Hydrides,” Appl. Phys. A 72, 167–186 (2001).
Y. Chen and J. S. Williams, “Formation of Metal Hydrides by Mechanical Alloying,” J. Alloys Compd. 217, 181–184 (1995).
A. Ye. Yermakov, N. V. Mushnikov, M. A. Uimin, et al., “Hydrogen Reaction Kinetics of Mg-Based Alloys Synthesized by Mechanical Milling,” J. Alloys Compd. 425, 367–372 (2006).
N. V. Mushnikov, A. E. Ermakov, M. A. Uimin, et al., “Kinetics of Interaction of Mg-Based Mechanically Activated Alloys with Hydrogen,” Fiz. Met. Metalloved. 102(4), 448–459 (2006) [Phys. Met. Metallogr. 102 (4), 421–431 (2006)].
L. T. Zhang, K. Ito, H. Inui, et al., “Hydrogen Absorption and Desorption in B 2 Single Phase Ti-22Al-27Nb Alloy before and after Deformation,” Acta Metal. Mater. 49, 751–758 (2001).
L. T. Zhang, K. Ito, H. Inui, et al., “Multiphase and Microstructure Effects on the Hydrogen Absorption/ Desorption Behavior of a Ti-22Al-27Nb Alloy,” Acta Metal. Mater. 49, 963–972 (2001).
K. Hashi, K. Ishikawa, K. Suzuki, and K. Ito, “Hydrogen Absorption and Desorption in the Binary Ti-Al System,” J. Alloys Compd. 330–332, 547–550 (2002).
L. T. Zhang, K. Ito, H. Inui, et al., “Reversible Hydrogen Absorption/Desorption and Related Phase Transformations in a Ti3 Al Alloy with the Stoichiometry Composition,” Acta Metal. Mater. 50, 4901–4912 (2002).
K. Ishikawa, K. Hashi, K. Suzuki, and K. Aoki, “Effect of Substitutional Elements on the Hydrogen Absorption-Desorption Properties of Ti3Al Compounds,” J. Alloys Compd. 314, 257–261 (2001).
L. T. Zang, K. Ito, H. Inui, et al., “Microstructure with Martensitic Features Induced by Absorption of a Large Amount of Hydrogen in B2 Single-Phase Ti-22Al-27Nb Alloy,” Acta Metal. Mater. 51, 781–788 (2003).
R. N. Eshchenko, O. A. Elkina, Yu. S. Bersenev, and V. P. Pilyugin, “Effect of Deuterium on the Phase Formation in the Ti3Al Intermetallic Compound,” Fiz. Met. Metalloved. 100(2), 42–50 (2005) [Phys. Met. Metallogr. 100 (2), 134–141 (2005)].
J. Huot, M.-L. Tremblay, and R. Schulz, “Synthesis of Nanocrystalline Hydrogen Storage Materials,” J. Alloys Compd. 356–357, 603–607 (2003).
R. A. Varin and T. Czujko, “The Effect of Atomic Volume on the Hydrogen Storage Capacity of Hexagonal Metals/Intermetallics,” Scr. Mater. 46, 531–535 (2002).
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Original Russian Text © N.V. Kazantseva, N.V. Mushnikov, A.G. Popov, V.A. Sazonova, P.B. Terent’ev, 2008, published in Fizika Metallov i Metallovedenie, 2008, Vol. 105, No. 5, pp. 492–502.
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Kazantseva, N.V., Mushnikov, N.V., Popov, A.G. et al. Use of mechanoactivation for obtaining hydrides of titanium aluminides. Phys. Metals Metallogr. 105, 460–470 (2008). https://doi.org/10.1134/S0031918X08050062
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DOI: https://doi.org/10.1134/S0031918X08050062