Abstract
The influence of perchloric acid on the spectral-luminescent characteristics of coumarin-7 and coumarin-30 in acetonitrile and ethanol is studied. A probable mechanism and methods of controlling the protonation of nitrogen atoms of the phenylimidazole fragment are discussed.
Similar content being viewed by others
References
G. Jones II and J. A. C. Jimenez, J. Photochem. Photobiol., Ser. B: Biol. 65, 5 (2001). doi 10.1016/S1011–1344(01)00236-6
M. V. Mina, I. P. Puzyk, and M. V. Puzyk, Opt. Spectrosc. 114, 244 (2013). doi 10.7868/S0030403413020207
M. V. Nikolaeva and M. V. Puzyk, Opt. Spectrosc. 116, 254 (2014). doi 10.7868/S0030403414020159
M. V. Nikolaeva and M. V. Puzyk, Opt. Spectrosc. 117, 589 (2014). doi 10.7868/S0030403414090190
M. V. Nikolaeva, E. A. Katlenok, M. S. Khakhalina, M. V. Puzyk, and K. P. Balashev, J. Phys.: Conf. Ser. 643, 012045 (2015). doi 10.1088/1742-6596/643/1/012045
S. Corrent, P. Hahn, G. Pohlers, T. J. Connolly, J. C. Scaiano, V. Fornes, and H. Garcia, J. Phys. Chem. B 102, 5852 (1998). doi 10.1021/jp981148w
I. Gyenes, Titration in Non-Aqueous Media (Akademiai Kiado, Budapest, 1967).
A. Gordon and R. Ford, The Chemist’s Companion, A Handbook of Practical Data. Techniques and References (Wiley, New York, 1972).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © M.V. Nikolaeva, M.V. Puzyk, 2017, published in Optika i Spektroskopiya, 2017, Vol. 122, No. 4, pp. 645–647.
Rights and permissions
About this article
Cite this article
Nikolaeva, M.V., Puzyk, M.V. The change of the spectral-luminescent properties of coumarin-7 and coumarin-30 upon protonation. Opt. Spectrosc. 122, 625–627 (2017). https://doi.org/10.1134/S0030400X17040178
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0030400X17040178