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Spectral and luminescent properties of N,N'-bis(5-bromosalicylidene)-1,3-propylenediamine and its zinc complex

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Abstract

Zn(II) complex with N,N'-bis(5-bromosalicylidene)-1,3-propylenediamine, which efficiently luminesce in the blue region of the visible spectrum, is synthesized for the first time. It is found that, at 293 K, azomethine and zinc complex fluoresce in both solution and the polycrystalline state. Fluorescence quantum yields of the compounds in diluted dimethylformamide and dimethylsulfoxide solutions are determined.

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References

  1. D. A. Garnovskii, A. S. Burlov, I. S. Vasil’chenko, A. I. Uraev, and E. V. Korshunova, Vestn. Yuzh. Nauch. Tsentr RAN 10 (3), 35 (2014).

    Google Scholar 

  2. S. Wang, Coord. Chem. Rev. 251, 79 (2001). doi 10.1016/S0010-8545(00)00403-3

    Article  Google Scholar 

  3. R. C. Evans, P. Douglas, and C. J. Winscom, Coord. Chem. Rev. 250, 2093 (2006). doi 10.1016/j.ccr.2006.02.007

    Article  Google Scholar 

  4. C. Perez-Bolivar, V. A. Montes, and P. Anzenbacher, Inorg. Chem. 45, 9610 (2006). doi 10.1021/ic061051l

    Article  Google Scholar 

  5. W.-Y. Wong, G.-L. Lu, L. Liu, J.-X. Shi, and J. Lin, Eur. J. Inorg. Chem., No. 10, 2066 (2004). doi 10.1002/ejic.200300677

    Article  Google Scholar 

  6. S.-L. Zheng, J.-P. Zhang, X.-M. Chen, Z.-L. Huang, Z.-Y. Lin, and W.-T. Wong, Chem.-Eur. J. 9, 3888 (2003). doi 10.1002/chem.200304855

    Article  Google Scholar 

  7. Ch. Reichardt, Solvents and Solvent Effects in Organic Chemistry (Wiley, Weinheim, 2003).

    Google Scholar 

  8. A. I. Kryukov and S. Ya. Kuchmii, Principles of Coordination Compounds Photochemistry (Naukova Dumka, Kiev, 1990) [in Russian].

    Google Scholar 

  9. P. V. Alexander and R. J. Sleet, Austral. J. Chem. 23, 1183 (1970). doi 10.1071/CH9701183

    Article  Google Scholar 

  10. Yu. A. Fialkov, Solvent as Control Facility of Chemical Process (Khimiya, Leningrad, 1990) [in Russian].

    Google Scholar 

  11. G. L. Estiu, A. H. Jubert, J. Costamagna, and J. Vargas, J. Mol. Struct.: THEOCHEM 367, 97 (1996). doi 10.1016/S0166-1280(96)04575-7

    Article  Google Scholar 

  12. C. T. Z. Ma, A. Lo, and A. Abdolmaleki, Org. Lett. 6, 3841 (2004). doi 10.1021/ol0483549

    Article  Google Scholar 

  13. R. Doca, H. Elias, W. Haase, M. Hüber, R. Klement, L. Müller, H. Paulus, I. Svoboda, and M. Valko, Inorg. Chim. Acta 278, 1016 (1998). doi 10.1016/S0020-1693(97)06175-6

    Google Scholar 

  14. H. Y. Shen, D. Z. Liao, Z. H. Jiang, et al., Chem. J. Chin. Univ. 20, 1017 (1999).

    Google Scholar 

  15. M. Green and P. A. Tasker, Inorg. Chim. Acta 5, 65 (1971). doi 10.1016/S0020-1693(00)95883-3

    Article  Google Scholar 

  16. O. V. Kotova, S. V. Eliseeva, A. S. Averjushkin, L. S. Lepnev, A. A. Vaschenko, A. Yu. Rogachev, A. G. Vitukhnovskii, and N. P. Kuzmina, Russ. Chem. Bull. 57, 1880 (2008). doi 10.1007/s11172-008-0254-x

    Article  Google Scholar 

  17. H. Joshi, F. S. Kamounah, C. Gooijer, G. van der Zwan, and L. Antonor, J. Photochem. Photobiol., A 152, 183 (2002). doi 10.1016/S1010-6030(02)00155-7

  18. K. Amimoto and T. Kawato, J. Photochem. Photobiol. C 6, 207 (2005). doi 10.1016/j.jphotochemrev.2005. 12.002

    Article  Google Scholar 

  19. A. Filarowski, J. Phys. Org. Chem. 18, 1002 (2005). doi 10.1002/poc.940

    Google Scholar 

  20. A. M. Golyakov, A. V. Shchukarev, L. P. Ardasheva, and A. N. Borisov, Russ. J. Gen. Chem. 83, 423 (2013). doi 10.1134/S1070363213030031

    Article  Google Scholar 

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Correspondence to A. N. Borisov.

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Original Russian Text © M.S. Svirikhin, M.V. Puzyk, A.N. Borisov, 2016, published in Optika i Spektroskopiya, 2016, Vol. 121, No. 3, pp. 371–376.

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Svirikhin, M.S., Puzyk, M.V. & Borisov, A.N. Spectral and luminescent properties of N,N'-bis(5-bromosalicylidene)-1,3-propylenediamine and its zinc complex. Opt. Spectrosc. 121, 343–347 (2016). https://doi.org/10.1134/S0030400X16090216

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  • DOI: https://doi.org/10.1134/S0030400X16090216

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