Skip to main content
SpringerLink
Log in

Deviation of S-O chemical bond of SO2 molecule

  • Spectroscopy of Atoms and Molecules
  • Published:
Optics and Spectroscopy Aims and scope Submit manuscript

Abstract

The force matrix of the SO2 molecule is calculated without using a priori assumptions on the nature of the force field. The calculations are performed using a comparatively new 3N-matrix method based on the experimental frequencies of characteristic normal vibrations of 32S16O2, 32S18O2, and 34S16O2 molecules. It is shown that the direction of the chemical bond between chemically bound S and O atoms does not coincide with the direction of the straight line that connects the nuclei of these atoms. The angle between these directions (deviation angle) is determined. In the approximation of harmonic vibrations, the deviation angle is Δ = 1.092°. The effect of the anharmonicity of vibrations on the deviation angle is evaluated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. U. Bilyu and B. A. Okhrimenko, Ukr. Fiz. Zh. 44(3), 326 (1999).

    Google Scholar 

  2. M. U. Bilyu, G. I. Gaididei, and B. A. Okhrimenko, Funct. Mater. 7(3), 543 (2000).

    Google Scholar 

  3. B. A. Okhrimenko and G. I. Gaididei, Ukr. Fiz. Zh. 48(7), 739 (2003).

    Google Scholar 

  4. M. U. Belyi, B. A. Okhrimenko, and S. M. Yablochkov, Izv. Vyssh. Uchebn. Zaved., Fiz., No. 4, 52 (1987).

  5. A. S. Davydov, Quantum Mechanics (Nauka, Moscow, 1973; Pergamon, New York, 1976) [in Russian].

    Google Scholar 

  6. B. A. Okhrimenko and K. S. Yablochkova, Ukr. Fiz. Zh. 52(6), 558 (2007).

    Google Scholar 

  7. M. U. Bilyu and B. A. Okhrimenko, Ukr. Fiz. Zh. 46(8), 825 (2001).

    Google Scholar 

  8. G. I. Gaididei and B. A. Okhrimenko, Visn. Kyiv Univ., Ser. Fiz., No. 4, 22 (2002).

  9. B. A. Okhrimenko, G. I. Gaididei, and D. M. Samoilenko, Proc. SPIE 5507, 184 (2002).

    Article  ADS  Google Scholar 

  10. M. U. Bilyu, G. I. Gaididei, B. A. Okhrimenko, V. P. Sakun, and D. M. Samoilenko, Ukr. Fiz. Zh. 46(12), 1256 (2001).

    Google Scholar 

  11. G. I. Gaididei, B. A. Okhrimenko, M. V. Shelekhova, and K. S. Yablochkova, Visn. Kyiv Univ., Ser. Fiz., No. 5, 16 (2003).

  12. B. A. Okhrimenko and K. S. Yablochkova, Visn. Kyiv Univ., Ser. Fiz., No. 4, 449 (2006).

  13. M. U. Bilyu and B. A. Okhrimenko, Ukr. Fiz. Zh. 46(4), 466 (2001).

    Google Scholar 

  14. B. A. Okhrimenko and D. M. Samoilenko, Visn. Kyiv Univ., Ser. Fiz., No. 4, 45 (2002).

  15. B. A. Okhrimenko, G. I. Gaididei, and D. M. Samoilenko, Funct. Mater. 11(1), 136 (2004).

    Google Scholar 

  16. B. A. Okhrimenko and D. M. Samoilenko, Ukr. Fiz. Zh. 50(6), 544 (2005).

    Google Scholar 

  17. L. M. Sverdlov, M. A. Kovner, and E. P. Krainov, Vibrational Spectra of Polyatomic Molecules (Nauka, Moscow, 1970; Wiley, New York, 1974).

    Google Scholar 

  18. A. H. Nielsen, R. D. Shelton, and W. H. Fletcher, J. Phys. Rad. 15, 604 (1954).

    Article  Google Scholar 

  19. A. Barbe and P. Jouve, J. Mol. Spectr. 38, 273 (1971).

    Article  ADS  Google Scholar 

  20. A. Zobov et al., Chem. Phys. Lett. 414, 193 (2005).

    Article  ADS  Google Scholar 

  21. C. H. Townes and A. L. Schawlow, Microwave Spectroscopy (McGraw-Hill, New York, 1955; Inostrannaya Literatura, Moscow, 1959).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Physics Department, Shevchenko National University, Kiev, 03127, Ukraine

    B. A. Okhrimenko & O. A. Yushko

Authors
  1. B. A. Okhrimenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. A. Yushko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to B. A. Okhrimenko.

Additional information

Original Russian Text © B.A. Okhrimenko, O.A. Yushko, 2011, published in Optika i Spektroskopiya, 2011, Vol. 110, No. 2, pp. 211–217.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Okhrimenko, B.A., Yushko, O.A. Deviation of S-O chemical bond of SO2 molecule. Opt. Spectrosc. 110, 184–190 (2011). https://doi.org/10.1134/S0030400X11020147

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0030400X11020147

Keywords

Search

Navigation