Abstract
Novel methods and device configurations for singlet oxygen and atomic iodine generation were proposed and investigated for operation of the chemical or discharge oxygen-iodine lasers (COIL/DOIL). A chemical centrifugal spray generator of singlet oxygen was developed, based on the conventional chlorine-basic hydrogen peroxide chemistry. Results of theoretical and experimental investigation of the generator parameters are presented and compared with parameters of other generator types. A design of experimental device for singlet oxygen generation by means of the hybrid DC arc and RF plasma jet is presented. An alternative method of atomic iodine generation by a radiofrequency discharge decomposition of iodine compounds like CH3I or CF3I is described employing advanced experimental configuration. Some representative experimental results of this investigation are presented.
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References
Final Report to the USAF/EOARD Research Contract FA8655-04-1-3021: Advanced Singlet Oxygen Generator for a COIL (January 2005).
O. Špalek, J. Hrubý, V. Jirásek, M. Čenský, J. Kodymová, and I. Picková, Proc. SPIE-Int. Soc. Opt. Eng. 63460 1 (2006).
Final Report to the USAF/EOARD Research Contract FA8655-05-C-4022: Advanced Singlet Oxygen Generator for a COIL (April 2008).
J. Kodymová, O. Špalek, V. Jirásek, M. Čenský, and I. Picková, in Proceedings of the 38th AIAA Plasmadynamics and Lasers Conference (Miami, USA, 2007), AIAA Paper 2007-4622.
O. Špalek, V. Jirásek, M. Čenský, J. Kodymová, and I. Picková, Proc. SPIE-Int. Soc. Opt. Eng. 7131 OU–1 (2008).
J. A. Blauer, S. A. Nunjee, K. A. Truesdell, et al., Appl. Phys. 62, 2508 (1987).
T. L. Rittenhouse, S. P. Phipps, and C. A. Helms, IEEE J. Quantum Electron. 35, 857 (1999).
K. R. Kendrick, C. A. Helms, and B. G. Quillen, IEEE J. Quantum Electron. 35, 1759 (1999).
M. V. Zagidullin, V. D. Nikolaev, M. I. Svistun, et al., Proc. SPIE-Int. Soc. Opt. Eng. 2702, 310 (1996).
I. Blayas, B. D. Barmashenko, D. Furman, et al., IEEE J. Quantum Electron. 32, 2051 (1996).
W. E. McDermott, J. C. Stephens, J. Vetrovec, and R. A. Dickerson, in Proceedings of the 28th AIAA Plas-madynamics and Lasers Conference (Atlanta, USA, 1997), AIAA Paper 97-2385.
I. M. Evdokimov, D. N. Vasiliev, A. V. Savin, and S. L. Druzhinin, Proc. SPIE-Int. Soc. Opt. Eng. 5777, 39 (2005).
W. J. Thayer, in Proceedings of the 23rd Plasmadynamics and Lasers Conference (Nashville, USA, 1992), AIAA Paper 92-3008.
S. Muto, M. Endo, K. Nanri, and T. Fujioka, Jpn J. Appl. Phys. 41, 5193 (2002).
A. A. Adamenkov, B. A. Vyskubenko, S. P. Ilyin, and S. P. Krukovski, Quantum Electron. 32, 490 (2002).
F. Wani, M. Endo, B. A. Vyskubenko, et al., IEEE J. Quantum Electron. 34, 2130 (1998).
V. D. Nikolaev, M. I. Svistun, M. V. Zagidullin, and G. D. Hager, Appl. Phys. Lett. 86, 25 (2005).
M. V. Zagidullin, V. D. Nikolaev, M. I. Svistun, and N. A. Khvatov, J. Eng. Phys. Therm. 80, 555 (2007).
J. Schmiedberger, V. Jirásek, J. Kodymová, and K. Rohlena, in Proceedings of the 38th AIAA Plasmadynamics and Lasers Conference (Miami, USA, 2007), AIAA Paper 2007-4239.
J. Schmiedberger, K. Rohlena, P. Filip, J. Gregor, M. Hrabovský, P. Křenek, V. Jirásek, and J. Kodymová, Proc. SPIE-Int. Soc. Opt. Eng. 7131 OU–1 (2008).
M. Venugopalan, Reactions under Plasma Conditions (Wiley, New York, 1971), Vol. II, p. 237.
V. P. Glushko, Thermodynamical Properties of Individual Compounds (Nauka, Moscow, 1962) [in Russian].
M. W. Chase, NIST-JANAF Thermodynamical Tables (NIST, New York, 1998).
T. J. Madden, G. D. Hager, A. I. Lampson, and P. G. Crowell, in Proceedings of the 30th AIAA Plasma-dynamics and Laser Conference (Norfolk, USA, 1999), AIAA Paper 99-3429.
D. Carroll and W. Solomon, Proc. SPIE-Int. Soc. Opt. Eng. 4184, 40 (2000).
J. Schmiedberger, V. Jirásek, M. Čenský, J. Kodymová, and I. Picková, Proc. SPIE-Int. Soc. Opt. Eng. 7131 OF–1 (2008).
Final Report to the USAF/EOARD Research Contract FA8655-06-1-3034: Discharge Generation of Atomic Iodine for a COIL (May 2008).
R. F. Tate, B. S. Hunt, C. A. Helms, et al., IEEE J. Quantum Electron. 31, 1632 (1995).
V. Jirásek, J. Schmiedberger, M. ensky, I. Pickova, J. Kodymová, and O. Špalek, Chemické Listy 102, 1327 (2008).
NIST Chemical Kinetic Database, http://kinet-ics.nist.gov.
L. G. Christophorou and J. K. J. Olthoff, Phys. Chem. Ref. Data 29, 553 (2000).
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Kodymová, J., Jirásek, V., Schmiedberger, J. et al. Research on chemical and discharge oxygen-iodine lasers. Opt. Spectrosc. 107, 816–825 (2009). https://doi.org/10.1134/S0030400X09110216
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DOI: https://doi.org/10.1134/S0030400X09110216