Abstract
Quartz glass samples with a thin photosensitive AgCl-Ag film, prepared by successive evaporation of AgCl (h AgCl ≈ 35 nm) and Ag (h Ag ≈ 8 nm) in vacuum have been investigated. A periodic structure with a period of d = 375 nm formed by Ag particles was obtained in films using a p-polarized laser beam (λ = 532 nm, P = 25 mW) at an angle of incidence of ϕ = 20°. After removing AgCl in a fixing agent, the periodic structure remained on the glass surface. Subsequent irradiation by a CO2 laser (λ = 10.6 µm, P ≈ 20 W) led to the implantation of this structure into the glass with the conservation of its period d and partial conservation of the related dichroism. The fact of implantation is confirmed by the high mechanical and chemical stability of the structure obtained. A possible implantation mechanism, taking into account the thermionic emission, Ag ionic transport, and the presence of free voids in the quartz glass and defects in its structural network, is discussed.
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R. A. Ganeev, A. I. Ryasnyanskiĭ, A. L. Stepanov, M. K. Kodirov, and T. Usmanov, Opt. Spektrosk. 95(6), 1034 (2003) [Opt. Spectrosc. 95, 967 (2003)].
U. Kreibig and M. Vollmer, Optical Properties of Metal Clusters (Springer, Berlin, 1995).
H. Hovel, S. Fritz, A. Hilder, U. Kreibig, and M. Vollmer, Phys. Rev. B 48, 18 178 (1993).
M. Antonello, G. W. Arnold, G. Battaglin, R. Bertoncello, E. Cattaruzza, P. Colombo, G. Mattei, P. Mazzoldi, and F. Trivillin, J. Mater. Chem. 8, 457 (1998).
L. Armelao, R. Bertoncello, E. Cattaruzza, S. Gialanella, S. Gross, G. Mattei, P. Mazzoldi, and E. Tondello, J. Mater. Chem. 12, 2401 (2002).
W. Cai, H. Hofmeister, T. Rainer, and W. Chen, J. Nanopart. Res. 3, 443 (2001).
A. L. Stepanov, Rev. Adv. Mater. Sci. 4, 123 (2003).
A. Nahal, H. R. M. Khalesifard, and J. Mostafavi-Amjad, Appl. Phys. B 79, 513 (2004).
M. Sendova, M. Sendova-Vassileva, J. C. Pivin, H. Hjfmeister, K. Coffey, and A. Warren, J. Nanosci. Nanotechnol. 6(3), 748 (2006).
L. A. Ageev, V. K. Miloslavsky, and E. D. Makovetsky, Opt. Spektrosk. 102(3), 489 (2007) [Opt. Spectrosc. 102, 442 (2007)].
L. A. Ageev, V. K. Miloslavsky, E. D. Makovetsky, K. Beloshenko, and A. V. Stronsky, Funct. Mater. 14(1), 24 (2007).
L. A. Ageev and V. K. Miloslavsky, Opt. Eng. 34(4), 960 (1995).
L. A. Ageev, V. K. Miloslavsky, H. I. Elashhab, and V. B. Blokha, Training Experiments and Demonstrations in Optics: A Textbook (KhNU, Kharkov, 2000) [in Russian].
V. K. Miloslavsky, Nonlinear Optics: A Textbook (KhNU, Kharkov, 2008) [in Russian].
P. V. Meĭklyar, Physical Processes in the Formation of Latent Photographic Images (Nauka, Moscow, 1972) [in Russian].
V. K. Leko and O. V. Mazurin, Properties of Quartz Glass (Nauka, Leningrad, 1985) [in Russian].
A. Feltz, Amorphe und Glasartige Anorganische Festörper (Verlag, Berlin, 1983; Mir, Moscow, 1986).
Theory, Technology, and Equipment of Diffusion Welding, Ed. by V. A. Bachin (Mashinostroenie, Moscow, 1991) [in Russian].
E. M. Voronkova, B. N. Grechushnikov, G. I. Distler, and I. P. Petrov, Optical Materials for IR Applications (Nauka, Moscow, 1965) [in Russian].
Properties of Elements: A Handbook, Ed. by M. E. Drits (Metallurgiya, Moscow, 1985) [in Russian].
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Original Russian Text © L.A. Ageev, K.S. Beloshenko, E.D. Makovetsky, V.K. Miloslavsky, 2009, published in Optika i Spektroskopiya, 2009, Vol. 107, No. 5, pp. 838–745.
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Ageev, L.A., Beloshenko, K.S., Makovetsky, E.D. et al. Implantation of periodic structures formed by silver particles into quartz glass. Opt. Spectrosc. 107, 796–802 (2009). https://doi.org/10.1134/S0030400X09110186
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DOI: https://doi.org/10.1134/S0030400X09110186