Abstract
A method for leaching rare earth elements from coal ash in the presence of elemental sulfur-oxidizing communities of acidophilic chemolithotrophic microorganisms was proposed. The optimal parameters determined for rare element leaching in reactors were as follows: temperature, 45°C; initial pH, 2.0; pulp density, 10%; and the coal ash to elemental sulfur ratio, 10 : 1. After ten days of leaching, 52.0, 52.6, and 59.5% of scandium, yttrium, and lanthanum, respectively, were recovered.
Similar content being viewed by others
References
Izquierdo, M. and Querol, X., Leaching behaviour of elements from coal combustion fly ash: an overview, Int. J. Coal Geol., 2012, vol. 94, pp. 54–66.
Khanra, S., Mallick, D., Dutta, S.N., and Chaudhuri, S.K., Studies on the phase mineralogy and leaching characteristics of coal fly ash, Water, Air, and Soil Pollution, 1998, vol. 107, nos. 1–4, pp. 251–275.
Zamana, L.V., Usmanova, L.I., and Usmanov, M.L., Hydrochemistry of the Chita TETs-1 ash heap sedimentation tank and the composition of subterranean water in the area of its infiltration influence, Vestn. Buryat. State Univ., 2010, no. 3, pp. 28–33.
Shishelova, T.I. and Samuseva, M.N., Application of ash-slag materials (ASW) of Irkutsk oblast thermal power plant as secondary raw materials, Uspekhi Sovr. Estestvozn, 2007, no. 8, pp. 24–26.
Dik, E.P. and Soboleva, A.N., Assessment of hazards from ash-slag waste of thermal power stations for environment and human health, in Zoloshlaki TES: udalenie, transport, pererabotka, skladirovanie (Ash and Slag of Thermal Power Stations: Removal, Transportation, Processing, and Storage), Proc. 2nd Sci.-Pract. Seminar, Moscow: MEI, 2009, pp. 65–68.
Salikhov, V.A., Assessment of economic effect at the regional level from recovery of precious metals from ash heaps of the Kemerovo oblast energy plants, Vestn. Kemerovo State Univ., 2012, no. 1, pp. 276–279.
Meretukov, M.A., Non-traditional sources for gold recovery, Tsvetnye metally, 2012, no. 12, pp. 51–56.
Syed S. Recovery of gold from secondary sources-a review, Hydrometallurgy, 2012, vols. 115–116, pp. 30–51.
Salikhov, V.A., Prospects for recovery of valuable nonferrous and rare metals from ash heaps of the Kemerovo oblast energy plants, Vestn. Tomsk State Univ., 2009, no. 327, pp. 163–168.
Salikhov, V.A., Prospects for development of small-scale high-technology industries, Vest. Kemesovo State Univ., 2011, no. 4, pp. 255–258.
Wang J., Ban, H., Teng, X., Wang, H., and Ladwig, K., Impacts of pH and ammonia on the leaching of Cu (II) and Cd (II) from coal fly ash, Chemosphere, 2006, vol. 64, no. 11, pp. 1892–1898.
Voloshina, O.A., Sulfur production and market in CIS countries, Mineral’nye Resursy Rossii. Ekonomika i Upravlenie, 2011, no. 4, pp. 68–73.
Pisz, J., Characterization of extremophilic sulfur oxidizing microbial communities inhabiting the sulfur blocks of Alberta’s oil sands, M. Sc. thesis, Saskatchewan, Dept. Soil Sci., Univ., of Saskatchewan, 2008.
Kondrat’eva, T.F., Pivovarova, T.A., Tsaplina, I.A., Bilaev, A.G., Muraviev, M.I., Zhuravleva, A.E., Grigor’eva, N.V., Melamud, V.S., and Moshchanetsky, P.V., Selection of communities of acidochemolithotrophic microorganisms with high oxidation rate of elemental sulfur, Yu.A. Ovchinnikov Bulletin Biotechnol. Phys. Chem. Biol., 2013, vol. 9, no 1, pp. 5–13.
Silverman, M.P. and Lundgren, D.C., Study on the chemoautotrophic iron bacterium Ferrobacillus ferrooxidans. I. An improved medium and harvesting procedure for securing high cell yield, J. Bacteriol., 1959, vol. 77, no. 5, pp. 642–647.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © M.I. Muravyov, A.G. Bulaev, V.S. Melamud, T.F. Kondrat’eva, 2015, published in Mikrobiologiya, 2015, Vol. 84, No. 2, pp. 216–224.
Rights and permissions
About this article
Cite this article
Muravyov, M.I., Bulaev, A.G., Melamud, V.S. et al. Leaching of rare earth elements from coal ashes using acidophilic chemolithotrophic microbial communities. Microbiology 84, 194–201 (2015). https://doi.org/10.1134/S0026261715010087
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0026261715010087