The Study of CrOx-Containing Catalysts Supported on ZrO2, CeO2, and CexZr(1–x)O2 in Isobutane Dehydrogenation

Abstract

Olefin hydrocarbons are valuable raw materials for petrochemical and polymer manufacturing. Highly effective, but toxic chromium-containing catalytic materials are the most widely used catalysts to obtain olefins in industry. In this regard, the urgent challenge to increase the efficiency of oil processing is to develop the catalysts with low content of harmful active component. In the present study, the catalysts with low chromium content (1 theoretical monolayer = 5 Cr atoms per nm2 of support) were synthesized by incipient wetness impregnation of the supports (Al2O3, ZrO2, CeO2, and CexZr(1–x)O2). The samples obtained were characterized by low-temperature nitrogen adsorption, X-ray diffraction and H2-temperature-programmed reduction methods. The catalytic properties of the catalysts were tested in isobutane dehydrogenation reaction. It was shown that the state of chromium on the surface is different over different supports. For the CrOx/CeO2 catalyst, the formation of Cr2O3 particles with low activity in the dehydrogenation reaction was observed. For other samples, a highly disperse X-ray amorphous state of chromium was characteristic. The catalyst based on CexZr(1–x)O2 was the most active in isobutane dehydrogenation reaction due to possible stabilization of chromium as Cr(V) state.

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References

  1. 1.

    Rashidi, M., Nikazar, M., Rahmani, M., and Mohamadghasemi, Z., Chem. Eng. Res. Des., 2015, vol. 95, p.239.

    Article  CAS  Google Scholar 

  2. 2.

    Pakhomov, N.A., Kashkin, V.N., Nemykina, E.I., Molchanov, V.V., Nadtochiy, V.I., and Noskov, A.S., Chem. Eng. J., 2009, vol. 154, p.185.

    Article  CAS  Google Scholar 

  3. 3.

    Shee, D. and Sayari, A., Appl. Catal., A., 2010, vol. 389, p.155.

    Article  CAS  Google Scholar 

  4. 4.

    Tan, S., Kim, S.-J., Moore, J.S., Liu, Y., Dixit, R.S., Pendergast, J.G., Sholl, D.S., Nair, S., and Jones, C.W., ChemCatChem, 2016, vol. 8, p.214.

    Article  CAS  Google Scholar 

  5. 5.

    Raju, G., Reddy, B.M., and Park, S.-E., J. CO2 Util., 2014, vol. 5, p.41.

    Article  CAS  Google Scholar 

  6. 6.

    Tan, S., Gil, L.B., Subramanian, N., Sholl, D.S., Nair, S., Jones, C.W., Moore, J.S., Liu, Y., Dixit, R.S., and Pendergast, J.G., Appl. Catal., A., 2015, vol. 498, pp. 167–175.

    Article  CAS  Google Scholar 

  7. 7.

    Rodemerck, U., Sokolov, S., Stoyanova, M., Bentrup, U., Linke, D., and Kondratenko, E.V., J. Catal., 2016, vol. 338, p.174.

    Article  CAS  Google Scholar 

  8. 8.

    Sattler, J.J.H.B., Gonzalez-Jimenez, I.D., Luo, L., Stears, B.A., Malek, A., Barton, D.G., Kilos, B.A., Kaminsky, M.P., Verhoeven, T.W.G.M., Koers, E.J., Baldus, M., and Weckhuysen, B.M., Angew. Chem., 2014, vol. 53, p. 9251.

    Article  CAS  Google Scholar 

  9. 9.

    Michorczyk, P., Kustrowski, P., Kolak, A., and Zimowska, M., Catal. Commun., 2013, vol. 35, p.95.

    Article  CAS  Google Scholar 

  10. 10.

    Wang, G., Sun, N., Gao, C., and Zhu, X., Appl. Catal., A, 2014, vol. 478, p.71.

    Article  CAS  Google Scholar 

  11. 11.

    Sattler, J.J.H.B., Ruiz-Martinez, J., Santillan-Jimenez, E., and Weckhuysen, B.M., Chem. Rev., 2014, vol. 114, p. 10613.

    Article  CAS  PubMed  Google Scholar 

  12. 12.

    Hakuli, A., Kytökivi, A., and Krause, O., Appl. Catal., A, 1999, vol. 4827, p.1.

    Google Scholar 

  13. 13.

    Fang, D., Zhao, J., Li, W., Fang, X., Yang, X., Ren, W., and Zhang, H., J. Energy Chem., 2015, vol. 24, p.101.

    Article  Google Scholar 

  14. 14.

    Gomez Sanz, S., McMillan, L., McGregor, J., Zeitler, J.A., Al-Yassir, N., Al-Khattaf, S., and Gladden, L.F., Catal. Sci. Technol., 2016, vol. 6, p. 1120.

    Article  CAS  Google Scholar 

  15. 15.

    Botavina, M.A., Evangelisti, C., Agafonov, Y.A., Gaidai, N.A., Panziera, N., Lapidus, A.L., and Martra, G., Chem. Eng. J., 2011, vol. 166, p. 1132.

    Article  CAS  Google Scholar 

  16. 16.

    Michorczyk, P., Ogonowski, J., and Zenczak, K., J. Mol. Catal. A: Chem., 2011, vol. 349, p.1.

    Article  CAS  Google Scholar 

  17. 17.

    Sloczynski, J., Grzybowska, B., Kozlowska, A., Samson, K., Grabowski, R., Kotarba, A., and Hermanowska, M., Catal. Today, 2011, vol. 169, p.29.

    Article  CAS  Google Scholar 

  18. 18.

    Vuurman, M.A., Wachs, I.E., Stufkens, D.J., and Oskam, A., J. Mol. Catal., 1993, vol. 80, p.209.

    Article  CAS  Google Scholar 

  19. 19.

    Mimura, N., Okamoto, M., Yamashita, H., Oyama, S.T., and Murata, K., J. Phys. Chem. B, vol. 110, p. 21764.

  20. 20.

    Ma, F., Chen, S., Li, Y., Zhou, H., Xu, A., and Lu, W., Appl. Surf. Sci., 2014, vol. 313, p.654.

    Article  CAS  Google Scholar 

  21. 21.

    Xu, L., Wang, Z., and Song, H., Catal. Commun., 2013, vol. 35, p.76.

    Article  CAS  Google Scholar 

  22. 22.

    Zhao, H., Song, H., and Chou, L., Microporous Mesoporous Mater., 2013, vol. 181, p.182.

    Article  CAS  Google Scholar 

  23. 23.

    De Rossi, S., Casaletto, M.P., Ferraris, G., Cimino, A., and Minelli, G., Appl. Catal., A, 1998, vol. 167, p.257.

    Article  Google Scholar 

  24. 24.

    Otroshchenko, T., Radnik, J., Schneider, M., Rodemerck, U., Linke, D., and Kondratenko, E.V., Chem. Commun., 2016, vol. 52, p. 8164.

    Article  CAS  Google Scholar 

  25. 25.

    Rezaei, M., Alavi, S.M., Sahebdelfar, S., and Yan, Z.-F., Powder Technol., 2006, vol. 168, p.59.

    Article  CAS  Google Scholar 

  26. 26.

    Bugrova, T.A., Litvyakova, N.N., and Mamontov, G.V., Kinet. Catal., 2015, vol. 56, no. 6, p.758.

    Article  CAS  Google Scholar 

  27. 27.

    Bekmukhamedov, G.E., Mukhamed’yarova, A.N., Egorova, S.R., and Lamberov, A.A., Catalysts, 2016, vol. 6, no. (10).

    Google Scholar 

  28. 28.

    Neri, G., Pistone, A., De Rossi, S., Rombi, E., Milone, C., and Galvagno, S., Appl. Catal., A, 2004, vol. 260, p.75.

    Article  CAS  Google Scholar 

  29. 29.

    Dittmar, A., Hoang, D.L., and Martin, A., Thermochim. Acta, 2008, vol. 470, p.40.

    Article  CAS  Google Scholar 

  30. 30.

    Moriceau, P., Grzybowska, B., Gengembre, L., and Barbaux, Y., Appl. Catal., A, 2000, vol. 199, p.73.

    Article  CAS  Google Scholar 

  31. 31.

    Martinez-Huerta, M.V., Deo, G., Luis, J., Fierro, G., and Banares, M.A., J. Phys. Chem., vol. 111, p. 18708.

  32. 32.

    Mullins, D.R., Surf. Sci., 2015, vol. 70, p.42.

    Article  CAS  Google Scholar 

  33. 33.

    Wei, C., Xue, F., Miao, C., Yue, Y., Yang, W., Hua, W., and Gao, Z., Chin. J. Chem., 2017, vol. 35, p.1619.

    Article  CAS  Google Scholar 

  34. 34.

    Nemykina, E.I., Pakhomov, N.A., Danilevich, V.V., Rogov, V.A., Zaikovskii, V.I., Larina, T.V., and Molchanov, V.V., Kinet. Catal., 2010, vol. 51, no. 6, pp. 898–906.

    Article  CAS  Google Scholar 

  35. 35.

    Cutrufello, M.G., De Rossi, S., Ferino, I., Monaci, R., Rombi, E., and Solinas, V., Thermochim. Acta, 2005, vol. 434, p.62.

    Article  CAS  Google Scholar 

  36. 36.

    Cavani, F., Koutyrev, M., Trifro, F., Bartolini, A., Ghisletti, D., Iezzi, R., Santucci, A., and Del Piero, G., J. Catal., 1996, vol. 158, p.236.

    Article  CAS  Google Scholar 

  37. 37.

    Hardcastle, F.D. and Wachs, I.E., J. Mol. Catal., 1988, vol. 46, p.173.

    Article  Google Scholar 

  38. 38.

    Fridman, V.Z., Xing, R., and Severance, M., Appl. Catal., A, 2016, vol. 523, p. 39.

    Article  CAS  Google Scholar 

Download references

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Correspondence to T. A. Bugrova.

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Original Russian Text © T.A. Bugrova, G.V. Mamontov, 2018, published in Kinetika i Kataliz, 2018, Vol. 59, No. 2, pp. 169–176.

The article was translated by the authors.

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Bugrova, T.A., Mamontov, G.V. The Study of CrOx-Containing Catalysts Supported on ZrO2, CeO2, and CexZr(1–x)O2 in Isobutane Dehydrogenation. Kinet Catal 59, 143–149 (2018). https://doi.org/10.1134/S0023158418020027

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Keywords

  • Cr-containing catalysts
  • ZrO2
  • CeO2
  • CexZr(1–x)O2
  • isobutane dehydrogenation