Effect of the metal−support interaction in Ag/CeO2 catalysts on their activity in ethanol oxidation


The interaction of silver with the surface of CeO2 in the Ag/CeO2 catalysts prepared by coprecipitation and impregnation techniques was studied by temperature-programmed reduction, X-ray diffraction, and high-resolution transmission electron microscopy. It was shown that coprecipitation technique led to formation of strong silver–support interaction and the epitaxy of silver particles (d 111 = 2.35 Å) on the surface of CeO2 (d 111 = 3.1 Å). This provided incresed catalytic activity in the oxidative dehydrogenation of ethanol at relatively low temperatures (a 15% conversion of ethanol with 100% selectivity for the formation of acetaldehyde was reached at 85°C). Above 130°C, the deep oxidation of ethanol to CO2 becomes the predominant direction of a catalytic reaction, and the Ag/CеО2 catalyst obtained by impregnation technique was most active in this region as a consequence of the weaker metal–support interaction.

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  1. 1.

    Qu, Z., Yu, F., Zhang, X., Wang, Y., and Gao, J., Chem. Eng. J., 2013, vol. 229, p. 522.

    CAS  Article  Google Scholar 

  2. 2.

    Fu, Q. and Wagner, T., Surf. Sci. Rep., 2007, vol. 62, p. 431.

    CAS  Article  Google Scholar 

  3. 3.

    Ma, L., Wang, D., Li, J., Bai, B., Fu, L., and Li, Y., Appl. Catal., B, 2014, vols. 148–149, p. 36.

    Google Scholar 

  4. 4.

    Chang, S., Li, M., Hua, Q., Zhang, L., Ma, Y., Ye, B., and Huang, W., J. Catal., 2012, vol. 293, p. 195.

    CAS  Article  Google Scholar 

  5. 5.

    Bera, P., Patil, K.C., and Hegde, M.S., Phys. Chem., 2000, vol. 2, p. 3715.

    CAS  Google Scholar 

  6. 6.

    Skaf, M., Aouad, S., Hany, S., Cousin, R., Abi-Aad, E., and Aboukais, A., J. Catal., 2014, vol. 320, p. 137.

    CAS  Article  Google Scholar 

  7. 7.

    Kayama, T., Yamazaki, K., and Shinjoh, H., J. Am. Chem. Soc., 2010, vol. 132, p. 13154.

    CAS  Article  Google Scholar 

  8. 8.

    Shimizu, K., Kawachi, H., and Satsuma, A., Appl. Catal., B, 2010, vol. 96, p. 169.

    CAS  Article  Google Scholar 

  9. 9.

    Aneggi, E., Llorca, J., Leitenburg, C., Dolcetti, G., and Trovarelli, A., Appl. Catal., B, 2009, vol. 91, p. 489.

    CAS  Article  Google Scholar 

  10. 10.

    Lee, C., Park, J., Shul, Y.-G., Einaga, H., and Teraoka, Y., Appl. Catal., B, 2015, vol. 174, p. 185.

    Article  Google Scholar 

  11. 11.

    Machida, M., Murata, Y., Kishikawa, K., Zhang, D., and Ikeue, K., Chem. Mater., 2008, vol. 20, p. 4489.

    CAS  Article  Google Scholar 

  12. 12.

    Yamazaki, K., Kayama, T., Dong, F., and Shinjoh, H., J. Catal., 2011, vol. 282, p. 289.

    CAS  Article  Google Scholar 

  13. 13.

    Leng, Q., Yang, D., Yang, Q., Hu, C., Kang, Y., Wang, M., and Hashim, M., Mater. Res. Bull., 2015, vol. 266.

    Google Scholar 

  14. 14.

    Wang, L., He, H., Yu, Y., Sun, L., Liu, S., Zhang, C., and He, L., J. Inorg. Biochem., 2014, vol. 135, p. 45.

    CAS  Article  Google Scholar 

  15. 15.

    Mamontov, G.V., Grabchenko, M.V., Sobolev, V.I., Zaikovskii, V.I., and Vodyankina, O.V., Appl. Catal., A, 2016, vol. 528, p. 161.

    CAS  Article  Google Scholar 

  16. 16.

    Mitsudome, T., Mikami, Y., Matoba, M., Mizugaki, T., Jitsukawa, K., and Kaneda, K., Angew. Chem., Int. Ed. Engl., 2012, vol. 51, p. 136.

    CAS  Article  Google Scholar 

  17. 17.

    Zhang, J., Li, L., Huang, X., and Li, G., J. Mater. Chem., 2012, vol. 22, p. 10480.

    CAS  Article  Google Scholar 

  18. 18.

    Bokii, G.K., Kristallokhimiya (Crystal Chemistry), Moscow: Nauka, 1971.

    Google Scholar 

  19. 19.

    Yao, H.C. and Yu-Yao, Y.F., J. Catal., 1984, vol. 86, p. 254.

    CAS  Article  Google Scholar 

  20. 20.

    Zhu, H., Qin, Z., Shan, W., Shen, W., and Wang, J., J. Catal., 2004, vol. 225, p. 267.

    CAS  Article  Google Scholar 

  21. 21.

    Mamontov, G.V., Dutov, V.V., Sobolev, V.I., and Vodyankina, O.V., Kinet. Catal., 2013, vol. 54, no. 4, p. 487.

    CAS  Article  Google Scholar 

  22. 22.

    Qu, Z., Huang, W., Cheng, M., and Bao, X., J. Phys. Chem. B, 2005, vol. 109, p. 15842.

    CAS  Article  Google Scholar 

  23. 23.

    Mamontov, G.V., Izaak, T.I., Magaev, O.V., Knyazev, A.S., and Vodyankina, O.V., J. Phys. Chem. A, 2011, vol. 85, no. 9, p. 1536.

    Google Scholar 

  24. 24.

    Scire, S., Riccobene, P.M., and Crisafulli, C., Appl. Catal., B, 2010, vol. 101, p. 109.

    CAS  Article  Google Scholar 

  25. 25.

    Feio, L.S.F., Hori, C.E., Damyanova, S., Noronha, F.B., Cassinelli, W.H., Marques, C.M.P., and Bueno, J.M.C., Appl. Catal., A, 2007, vol. 316, p. 107.

    CAS  Article  Google Scholar 

  26. 26.

    Acerbi, N., Edman, TsangS.C., Jones, G., Golunski, S., and Collier, P., Angew. Chem., Int. Ed. Engl., 2013, vol. 52, p. 7737.

    CAS  Article  Google Scholar 

  27. 27.

    Liotta, L.F., Longo, A., Macaluso, A., Martorana, A., Pantaleo, G., Venezia, A.M., and Deganello, G., Appl. Catal., B, 2004, vol. 48, p. 133.

    CAS  Article  Google Scholar 

  28. 28.

    Mullins, D.R., Surf. Sci. Rep., 2015, vol. 70, p. 42.

    CAS  Article  Google Scholar 

  29. 29.

    Mitsudome, T., Noujima, A., Mikami, Y., Mizugaki, T., Jitsukawa, K., and Kaneda, K., Angew Chem., 2010, vol. 122, p. 5677.

    Article  Google Scholar 

  30. 30.

    Mikami, Y., Noujima, A., Mitsudome, T., Mizugaki, T., Jitsukawa, K., and Kaneda, K., Chem. Lett., 2010, vol. 39, p. 223.

    CAS  Article  Google Scholar 

  31. 31.

    Shimizu, K., Sugino, K., Sawabe, K., and Satsuma, A., Chem. Eur. J., 2009, vol. 15, p. 2341.

    CAS  Article  Google Scholar 

  32. 32.

    Vayssilov, G.N., Lykhach, Y., Migani, A., Staudt, T., Petrova, G.P., Tsud, N., Skala, T., Bruix, A., Illas, F., Prince, K.C., Matolin, V., Neyman, K.M., and Libuda, J., Nat. Mater., 2011, vol. 10, p. 310.

    CAS  Article  Google Scholar 

  33. 33.

    Dutov, V.V., Mamontov, G.V., Zaikovskii, V.I., and Vodyankina, O.V., Catal. Today, 2016, vol. 278, p. 150.

    CAS  Article  Google Scholar 

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Correspondence to M. V. Grabchenko.

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Original Russian Text © M.V. Grabchenko, G.V. Mamontov, V.I. Zaikovskii, O.V. Vodyankina, 2017, published in Kinetika i Kataliz, 2017, Vol. 58, No. 5, pp. 654–661.

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Grabchenko, M.V., Mamontov, G.V., Zaikovskii, V.I. et al. Effect of the metal−support interaction in Ag/CeO2 catalysts on their activity in ethanol oxidation. Kinet Catal 58, 642–648 (2017). https://doi.org/10.1134/S0023158417050056

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  • Ag/CeO2 catalysts
  • metal−support interaction
  • ethanol oxidation