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Study of Pt/MgAlO x catalysts in n-decane dehydrogenation

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Abstract

The properties of Pt/MgAlO x catalysts based on aluminum–magnesium layered hydroxides have been investigated in n-decane dehydrogenation. The n-decene formation selectivity depends on the Mg/Al ratio in the support, on the platinum complex binding conditions, and on the platinum content of the catalyst. Increasing the proportion of magnesium decreases the number of acid cites in the support and changes the properties of supported platinum. As a result, the n-decene formation selectivity under the appropriate conditions reaches 90% without a modifier added.

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Authors and Affiliations

  1. Institute of Hydrocarbons Processing, Siberian Branch, Russian Academy of Sciences, Omsk, 644040, Russia

    O. B. Belskaya, L. N. Stepanova, T. I. Gulyaeva, D. V. Golinskii, A. S. Belyi & V. A. Likholobov

  2. Omsk State Technical University, Omsk, 644050, Russia

    O. B. Belskaya, A. S. Belyi & V. A. Likholobov

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  1. O. B. Belskaya
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  2. L. N. Stepanova
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  3. T. I. Gulyaeva
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  4. D. V. Golinskii
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  5. A. S. Belyi
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  6. V. A. Likholobov
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Correspondence to O. B. Belskaya.

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Original Russian Text © O.B. Belskaya, L.N. Stepanova, T.I. Gulyaeva, D.V. Golinskii, A.S. Belyi, V.A. Likholobov, 2015, published in Kinetika i Kataliz, 2015, Vol. 56, No. 5, pp. 663–671.

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Belskaya, O.B., Stepanova, L.N., Gulyaeva, T.I. et al. Study of Pt/MgAlO x catalysts in n-decane dehydrogenation. Kinet Catal 56, 655–662 (2015). https://doi.org/10.1134/S0023158415050018

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