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Mechanochemical synthesis of nanocrystalline nickel-molybdenum compounds, their morphology and application in catalysis: I. Effect of the Ni: Mo atomic ratio on the structure and properties of nickel-molybdenum compounds prepared under mechanochemical synthesis conditions

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Abstract

Mechanochemical activation in high-energy planetary activators was used for the preparation of highly dispersed nickel-molybdenum compounds. Nickel hydroxocarbonate [NiCO3 · 2Ni(OH)2 · nH2O] and ammonium paramolybdate [(NH4)6Mo7O24 · 4H2O] were chosen as starting compounds. The effect of the Ni: Mo atomic ratio on the composition and structure of products formed in the process of mechanochemical activation followed by calcination was studied. It was found that, at the Ni: Mo atomic ratios of 1.0 and 1.4, the mechanically activated product after calcination at 520°C contained 70–100% β-NiMoO4, which is a stable phase at temperatures lower than 180°C.

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References

  1. Pillay, B., Mathebula, M.R., and Friedrich, H.B., Appl. Catal., A, 2009, vol. 361, p. 57.

    Article  CAS  Google Scholar 

  2. Sleihgt, W. and Chamberland, B.L., Inorg. Chem., 1968, vol. 7, p. 1672.

    Article  Google Scholar 

  3. Plyasova, L.M., Ivanchenkov, I.Yu., Andrushkevich, M.M., Buyanov, R.A., Interberg, I.Sh., Khramova, G.A., Karakchiev, L.G., Kustova, G.N., Stepanov, G.A., Tsailingol’d, A.L., and Pilipenko, F.S., Kinet. Katal., 1973, vol. 14, no. 4, p. 1010.

    CAS  Google Scholar 

  4. Mazzocchia, C., Del Rosso, R., and Centola, P., An. Quim., 1980, vol. 79, p. 108.

    Google Scholar 

  5. Pilipenko, F.S. and Stepanov, G.A., Kinet. Katal., 1976, vol. 17, no. 4, p. 842.

    Google Scholar 

  6. Chaturvedi, S., Podriguez, J.A., Hanson, J.C., Albornoz, F., and Brito, J.L., Properties of Pure and Sulfided NiMoO4 and CoMoO4 Catalysts: TPR, XANES, and Time-Resolved XRD Studies. http://www.mrs.org/s-mrs/inex.asp

  7. Levin, D., Soled, S.L., and Ying, J.Y., Inorg. Chem., 1996, vol. 35, p. 4191.

    Article  CAS  Google Scholar 

  8. Brito, J.L., Barbosa, A.L., Albornoz, A., Seveino, F., and Laine, J., Catal. Lett., 1994, vol. 26, p. 329.

    Article  CAS  Google Scholar 

  9. Brito, J.L. and Barbosa, A.L., J. Catal., 1997, vol. 171, p. 329.

    Article  Google Scholar 

  10. Laine, J. and Pratt, K.C., React. Kinet. Catal. Lett., 1979, vol. 10, p. 207.

    Article  CAS  Google Scholar 

  11. US Patent 6534437 B2, 2003.

  12. Molchanov, V.V. and Buyanov, R.A., Usp. Khim., 2000, vol. 69, no. 5, p. 476.

    Google Scholar 

  13. Huirache-Acuna, R., Flores, Z.M.I., Albiter, M.A., Estrada-Guel, I., Ornelas, C., Paraguay-Delgado, F., Rico, J.L., Bejar-Gomez, L., Alonso-Nunez, G., and Martinez-Sanchez, R., J. Mater. Online, 2006, vol. 2. doi 10.2240/azoiomo0224

  14. Avakumov, E.G., Khim. Interes. Ust. Razv., 1994, no. 2, p. 541.

  15. Duplyakin, V.K., Baklanova, O.N., Chirkova, O.A., Antonicheva, N.V., Arbuzov, A.B., Voitenko, N.N., Drozdov, V.A., and Likholobov, V.A., Kinet. Catal., 2010, vol. 51, no. 1, p. 126.

    Article  CAS  Google Scholar 

  16. Madeira, L.M., Portela, M.F., and Mazzocchia, C., Catal. Rev., 2004, vol. 45, no. 1, p. 53.

    Article  Google Scholar 

  17. Krylov, O.V. and Kiselev, V.F., Adsorbtsiya i kataliz na perekhodnykh metallakh i ikh oksidakh (Adsorption and Catalysis on Transition Metals and Their Oxides), Moscow: Khimiya, 1988.

    Google Scholar 

  18. Sovremennaya kolebatel’naya spektroskopiya neorganicheskikh soedinenii (Contemporary Vibrational Spectroscopy of Inorganic Compounds), Yurchenko, E.N., Ed., Novosibirsk: Nauka, 1990.

    Google Scholar 

  19. Yurchenko, E.N., Kustova, T.N., and Batsanov, S.S., Kolebatel’nye spektry neorganicheskikh soedinenii (Vibrational Spectra of Inorganic Compounds), Novosibirsk: Nauka, 1981.

    Google Scholar 

  20. Andrushkevich, M.M., Buyanov, R.A., Khramova, G.A., Sitnikov, V.G., Itenberg, I.Sh., Plyasova, L.M., Kustov, G.N., Stepanov, G.A., Tsailingol’d, A.L., and Pilipenko, F.S., Kinet. Katal., 1973, vol. 14, no. 4, p. 1015.

    CAS  Google Scholar 

  21. Levin, D. and Ying, J.Y., J. Electroceram., 1999, vol. 3, no. 1, p. 25.

    Article  CAS  Google Scholar 

  22. Levin, D., Soled, S.L., and Ying, J.Y., Chem. Mater., 1996, vol. 8, p. 836.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Hydrocarbon Processing, Siberian Branch, Russian Academy of Sciences, Omsk, 644040, Russia

    O. A. Knyazheva, O. N. Baklanova, A. V. Lavrenov, V. A. Drozdov, N. N. Leont’eva, M. V. Trenikhin, A. B. Arbuzov & V. A. Likholobov

  2. Omsk State Technical University, Omsk, Russia

    O. N. Baklanova, V. A. Drozdov & V. A. Likholobov

Authors
  1. O. A. Knyazheva
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  2. O. N. Baklanova
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  3. A. V. Lavrenov
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  4. V. A. Drozdov
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  5. N. N. Leont’eva
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  6. M. V. Trenikhin
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  7. A. B. Arbuzov
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  8. V. A. Likholobov
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Correspondence to O. A. Knyazheva.

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Original Russian Text © O.A. Knyazheva, O.N. Baklanova, A.V. Lavrenov, V.A. Drozdov, N.N. Leont’eva, M.V. Trenikhin, A.B. Arbuzov, V.A. Likholobov, 2011, published in Kinetika i Kataliz, 2011, Vol. 52, No. 6, pp. 910–919.

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Knyazheva, O.A., Baklanova, O.N., Lavrenov, A.V. et al. Mechanochemical synthesis of nanocrystalline nickel-molybdenum compounds, their morphology and application in catalysis: I. Effect of the Ni: Mo atomic ratio on the structure and properties of nickel-molybdenum compounds prepared under mechanochemical synthesis conditions. Kinet Catal 52, 886–895 (2011). https://doi.org/10.1134/S0023158411060097

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  • DOI: https://doi.org/10.1134/S0023158411060097

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