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Catalytic properties of supramolecular systems based on polyoxyethylated calixarenes and amines

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Abstract

The rate of carboxylic ester cleavage by amphiphilic low-molecular-weight and polymeric amines in the presence of polyoxyethylated calix[4]arenes with different degrees of oxyethylation is determined by the formation of mixed aggregates, by the shift of pK a of the amine, and the character of the distribution of the reactants in functional micelles. All of the systems show a high substrate specificity. In the case of octyl- and decylamines, the reaction of p-nitrophenyl acetate is catalyzed and the reaction of more hydrophobic p-nitrophenyl laurate is inhibited. An opposite situation is observed in the systems based on branched polyethyleneimine: the reaction of p-nitrophenyl acetate is inhibited and the process involving p-nitrophenyl laurate is accelerated.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, Kazan, 420083, Tatarstan, Russia

    A. B. Mirgorodskaya, E. I. Yatskevich, Yu. R. Kudryashova, S. E. Solov’eva, I. S. Antipin, L. Ya. Zakharova & A. I. Konovalov

Authors
  1. A. B. Mirgorodskaya
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  2. E. I. Yatskevich
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  3. Yu. R. Kudryashova
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  4. S. E. Solov’eva
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  5. I. S. Antipin
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  6. L. Ya. Zakharova
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  7. A. I. Konovalov
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Correspondence to A. B. Mirgorodskaya.

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Original Russian Text © A.B. Mirgorodskaya, E.I. Yatskevich, Yu.R. Kudryashova, S.E. Solov’eva, I.S. Antipin, L.Ya. Zakharova, A.I. Konovalov, 2011, published in Kinetika i Kataliz, 2011, Vol. 52, No. 4, pp. 540–546.

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Mirgorodskaya, A.B., Yatskevich, E.I., Kudryashova, Y.R. et al. Catalytic properties of supramolecular systems based on polyoxyethylated calixarenes and amines. Kinet Catal 52, 529–535 (2011). https://doi.org/10.1134/S0023158411040082

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  • DOI: https://doi.org/10.1134/S0023158411040082

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